A. B. Kuznetsov, A. Y. Jamous, V. A. Svetlichnyi, V. S. Shevchenko, A. E. Kokh, Yu. M. Andreev, K. A. Kokh
{"title":"Sr3B2O6-YbBO3 系统固溶体的发光特性","authors":"A. B. Kuznetsov, A. Y. Jamous, V. A. Svetlichnyi, V. S. Shevchenko, A. E. Kokh, Yu. M. Andreev, K. A. Kokh","doi":"10.1134/S0022476624080031","DOIUrl":null,"url":null,"abstract":"<p>The Sr<sub>3</sub>B<sub>2</sub>O<sub>6</sub>–YbBO<sub>3</sub> diagram was constructed based on samples obtained by the solid-state synthesis. In the system YbBO<sub>3</sub>, Sr<sub>3</sub>Yb(BO<sub>3</sub>)<sub>3</sub>, Sr<sub>3</sub>Yb<sub>2</sub>(BO<sub>3</sub>)<sub>4</sub> and Sr<sub>3</sub>B<sub>2</sub>O<sub>6</sub> phases were identified by XRD analysis. Diffusion experiments showed formation of solid solutions between all compounds. These solid solutions demonstrate typical near-infrared luminescence in the range of 960-1020 nm, characteristic of Yb<sup>3+</sup> and related to <sup>2</sup><i>F</i><sub>5/2</sub> → <sup>2</sup><i>F</i><sub>7/2</sub> transitions in ytterbium ions.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 8","pages":"1502 - 1512"},"PeriodicalIF":1.2000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Luminescence Properties of Solid-Solutions in Sr3B2O6–YbBO3 System\",\"authors\":\"A. B. Kuznetsov, A. Y. Jamous, V. A. Svetlichnyi, V. S. Shevchenko, A. E. Kokh, Yu. M. Andreev, K. A. Kokh\",\"doi\":\"10.1134/S0022476624080031\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The Sr<sub>3</sub>B<sub>2</sub>O<sub>6</sub>–YbBO<sub>3</sub> diagram was constructed based on samples obtained by the solid-state synthesis. In the system YbBO<sub>3</sub>, Sr<sub>3</sub>Yb(BO<sub>3</sub>)<sub>3</sub>, Sr<sub>3</sub>Yb<sub>2</sub>(BO<sub>3</sub>)<sub>4</sub> and Sr<sub>3</sub>B<sub>2</sub>O<sub>6</sub> phases were identified by XRD analysis. Diffusion experiments showed formation of solid solutions between all compounds. These solid solutions demonstrate typical near-infrared luminescence in the range of 960-1020 nm, characteristic of Yb<sup>3+</sup> and related to <sup>2</sup><i>F</i><sub>5/2</sub> → <sup>2</sup><i>F</i><sub>7/2</sub> transitions in ytterbium ions.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"65 8\",\"pages\":\"1502 - 1512\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-09-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624080031\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624080031","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Luminescence Properties of Solid-Solutions in Sr3B2O6–YbBO3 System
The Sr3B2O6–YbBO3 diagram was constructed based on samples obtained by the solid-state synthesis. In the system YbBO3, Sr3Yb(BO3)3, Sr3Yb2(BO3)4 and Sr3B2O6 phases were identified by XRD analysis. Diffusion experiments showed formation of solid solutions between all compounds. These solid solutions demonstrate typical near-infrared luminescence in the range of 960-1020 nm, characteristic of Yb3+ and related to 2F5/2 → 2F7/2 transitions in ytterbium ions.
期刊介绍:
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.