基于 PVK:rGO 复合材料的 Memristor 器件的斑点图谱分析

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-08-26 DOI:10.1002/mame.202400213
Ramin Jamali, Madeh Sajjadi, Babak Taherkhani, Davood Abbaszadeh, Ali‐Reza Moradi
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引用次数: 0

摘要

这种忆阻器有望成为神经形态系统和开关应用的基础器件。在不对称电极(ITO/PVK:rGO/Al)之间由聚(N-乙烯基咔唑)和还原石墨烯复合材料夹层制成的器件表现出双稳态电阻开关行为。通过控制掺杂的氧化石墨烯可以优化忆阻器的性能。为了评估器件在导通和关断状态之间切换时的性能,光学表征方法因其非破坏性和远程性而大有可为。为此,本文介绍了斑点模式(SP)分析。SP 包含大量有关其生成机制的信息,可通过统计分析提取出来。我们获取了 PVK:rGO 在原位不同状态下的 SPs,并研究了其传导机制。统计参数的变化归因于 PVK:rGO 在物理开关机制方面的电阻状态。反过来,电阻/传导状态又取决于 PVK:rGO Memristors 的活性和特性,以及载流子密度变化引起的额外非均匀性。本光学方法可作为一种台式设备,在类似设备运行期间对其进行表征。
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Speckle Pattern Analysis of PVK:rGO Composite Based Memristor Device
The memristors are expected to be fundamental devices for neuromorphic systems and switching applications. The device made of a sandwiched layer of poly(N‐ vinylcarbazole) and reduced graphene composite between asymmetric electrodes (ITO/PVK:rGO/Al) exhibits bistable resistive switching behavior. The performance of the memristor can be optimized by controlling the doped graphene oxide. To assess the device performance when it switches between ON and OFF states, optical characterization approaches are highly promising due to their non‐destructive and remote nature. Here, speckle pattern (SP) analysis to this end is introduced. SPs include a huge amount of information about their generating mechanism, which is extracted through statistical elaboration. SPs of the PVK:rGO in different states in situ and examine the conduction mechanism is acquired. The variations in the statistical parameters are attributed to the resistance state of the PVK:rGO with regard to the physical switching mechanism. The resistance/conduction state, in turn, depends on the activity and properties of PVK:rGO memristors, as well as the additional non‐uniformities induced through the variations of density of carriers. The present optical methodology can be potentially served as a bench‐top device for characterization purposes of similar devices during their operating.
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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