Thermodynamic Properties of Lutetium Stannate Lu2Sn2O7 in the Temperature Range of 0–1871 K

Abstract

Lutetium stannate with a pyrochlore structure was synthesized using solid state reaction. The heat capacity of polycrystalline Lu₂Sn₂O₇ in the temperature range of 7.99–1871 K was measured by adiabatic and differential scanning calorimetry methods. Entropy, enthalpy change, and derived Gibbs energy were calculated from the smoothed heat capacity data. The Gibbs free energy of Lutetium stannate from elements was estimated, using the Δ_fS°(Т) values obtained in this work and the Δ_fH°(Т) values known from the literature. The temperature dependence of the cubic crystal lattice parameter and the value of the coefficient of thermal expansion in the temperature range of 300–1273 K were determined by high-temperature X-ray diffraction.