基于硼酸铋钡玻璃和 Er:YAG 的玻璃陶瓷合成过程中的化学和相变分析

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Inorganic Chemistry Pub Date : 2024-08-23 DOI:10.1134/s0036023624601399
A. D. Plekhovich, A. M. Kut’in, K. V. Balueva, E. E. Rostokina, M. E. Komshina, K. F. Shumovskaya
{"title":"基于硼酸铋钡玻璃和 Er:YAG 的玻璃陶瓷合成过程中的化学和相变分析","authors":"A. D. Plekhovich, A. M. Kut’in, K. V. Balueva, E. E. Rostokina, M. E. Komshina, K. F. Shumovskaya","doi":"10.1134/s0036023624601399","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>An original combination of thermal activation with exposure to a strong nonuniform electric field transforms a multicomponent solution to a precursor. The transformation of an aerosol into a finished mixture eliminates the stages of gel formation, long-term gel drying, and subsequent contaminating milling, while providing the molecular level of components mixing inherent in the sol–gel method. The phase, chemical, and other thermal manifestations in the bismuth barium borate part (0.2Bi<sub>2</sub>O<sub>3</sub>–0.6B<sub>2</sub>O<sub>3</sub>–0.2BaO) of the batch, the (Er<sub>0.5</sub>Y<sub>0.5</sub>)AG components batch, and the batch precursor, which initially combined all necessary components of glass ceramics, were studied by simultaneous thermal analysis (STA). The Gibbs energy minimization was used to determine the formation conditions of garnet and yttrium borate crystalline phases, identified by X-ray powder diffraction (XRD) in glass ceramic samples formed from ultrafine batches at various temperatures.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Analysis of Chemical and Phase Transformations during the Synthesis of Glass Ceramics Based on Bismuth Barium Borate Glass and Er:YAG\",\"authors\":\"A. D. Plekhovich, A. M. Kut’in, K. V. Balueva, E. E. Rostokina, M. E. Komshina, K. F. Shumovskaya\",\"doi\":\"10.1134/s0036023624601399\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>An original combination of thermal activation with exposure to a strong nonuniform electric field transforms a multicomponent solution to a precursor. The transformation of an aerosol into a finished mixture eliminates the stages of gel formation, long-term gel drying, and subsequent contaminating milling, while providing the molecular level of components mixing inherent in the sol–gel method. The phase, chemical, and other thermal manifestations in the bismuth barium borate part (0.2Bi<sub>2</sub>O<sub>3</sub>–0.6B<sub>2</sub>O<sub>3</sub>–0.2BaO) of the batch, the (Er<sub>0.5</sub>Y<sub>0.5</sub>)AG components batch, and the batch precursor, which initially combined all necessary components of glass ceramics, were studied by simultaneous thermal analysis (STA). The Gibbs energy minimization was used to determine the formation conditions of garnet and yttrium borate crystalline phases, identified by X-ray powder diffraction (XRD) in glass ceramic samples formed from ultrafine batches at various temperatures.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-08-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1134/s0036023624601399\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0036023624601399","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

摘要

摘要 热活化与暴露于强不均匀电场的独创组合将多组分溶液转化为前驱体。将气溶胶转化为成品混合物,省去了凝胶形成、长期凝胶干燥和随后的污染研磨等阶段,同时提供了溶胶-凝胶法固有的分子级成分混合。通过同步热分析(STA)研究了批次中的硼酸铋钡部分(0.2Bi2O3-0.6B2O3-0.2BaO)、(Er0.5Y0.5)AG 成分批次和批次前体(最初结合了玻璃陶瓷的所有必要成分)中的相、化学和其他热表现。通过 X 射线粉末衍射 (XRD),确定了在不同温度下由超细批次形成的玻璃陶瓷样品中石榴石和硼酸钇结晶相的形成条件,并利用吉布斯能最小化法确定了这些结晶相的形成条件。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Analysis of Chemical and Phase Transformations during the Synthesis of Glass Ceramics Based on Bismuth Barium Borate Glass and Er:YAG

Abstract

An original combination of thermal activation with exposure to a strong nonuniform electric field transforms a multicomponent solution to a precursor. The transformation of an aerosol into a finished mixture eliminates the stages of gel formation, long-term gel drying, and subsequent contaminating milling, while providing the molecular level of components mixing inherent in the sol–gel method. The phase, chemical, and other thermal manifestations in the bismuth barium borate part (0.2Bi2O3–0.6B2O3–0.2BaO) of the batch, the (Er0.5Y0.5)AG components batch, and the batch precursor, which initially combined all necessary components of glass ceramics, were studied by simultaneous thermal analysis (STA). The Gibbs energy minimization was used to determine the formation conditions of garnet and yttrium borate crystalline phases, identified by X-ray powder diffraction (XRD) in glass ceramic samples formed from ultrafine batches at various temperatures.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
期刊最新文献
Luminescence Features of Multicomponent Cubic Fluoride Pyrochlores Doped with Europium Ions Synthesis and Thermodynamic Properties of Thulium Titanate Carboxonium Derivatives of closo-Decaborate Anion [2,6-B10H8O2CC6H4R]– Based on Aromatic Carboxylic Acids: Synthesis and Physicochemical Properties Isotope Effect in IR Spectra of Highly Enriched Amorphous Silicon Dioxide ASiO2 (A = 28, 29, 30) Synthesis, Crystal Structure, and Thermodynamic Properties of Ca3Y2Ge3O12
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1