A. A. Kolodina, O. P. Demidov, L. D. Popov, I. V. Dubonosova, E. S. Khodykina, A. V. Skorova, S. B. Zaichenko, I. G. Borodkina, A. D. Dubonosov, A. V. Metelitsa, V. G. Vlasenko
{"title":"4-[(蒽-9′-亚甲基)氨基]-5-R-2,4-二氢-3H-1,2,4-三唑-3-硫酮的合成与结构","authors":"A. A. Kolodina, O. P. Demidov, L. D. Popov, I. V. Dubonosova, E. S. Khodykina, A. V. Skorova, S. B. Zaichenko, I. G. Borodkina, A. D. Dubonosov, A. V. Metelitsa, V. G. Vlasenko","doi":"10.1134/S0022476624080146","DOIUrl":null,"url":null,"abstract":"<p>By the condensation of 4-amino-5-<i>R</i>-2,4-dihydro-3<i>H</i>-1,2,4-triazole-3-thiones with anthracene-9- carbaldehyde, respective 4-[(anthracene-9′-ylmethylene)amine)]-5-<i>R</i>-2,4-dihydro-3<i>H</i>-1,2,4-triazole-3-thiones are prepared and structurally characterized by NMR, UV, IR spectroscopies, high-resolution mass spectrometry, and single crystal XRD. The effect of a substituent at position 5 in triazole moieties of azomethines obtained on their head-to-head or head-to-tail crystal packings is determined.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 8","pages":"1631 - 1640"},"PeriodicalIF":1.2000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure of 4-[(anthracene-9′-ylmethylene)amino]-5-R-2,4-Dihydro-3H-1,2,4-Triazole-3-Thiones\",\"authors\":\"A. A. Kolodina, O. P. Demidov, L. D. Popov, I. V. Dubonosova, E. S. Khodykina, A. V. Skorova, S. B. Zaichenko, I. G. Borodkina, A. D. Dubonosov, A. V. Metelitsa, V. G. Vlasenko\",\"doi\":\"10.1134/S0022476624080146\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>By the condensation of 4-amino-5-<i>R</i>-2,4-dihydro-3<i>H</i>-1,2,4-triazole-3-thiones with anthracene-9- carbaldehyde, respective 4-[(anthracene-9′-ylmethylene)amine)]-5-<i>R</i>-2,4-dihydro-3<i>H</i>-1,2,4-triazole-3-thiones are prepared and structurally characterized by NMR, UV, IR spectroscopies, high-resolution mass spectrometry, and single crystal XRD. The effect of a substituent at position 5 in triazole moieties of azomethines obtained on their head-to-head or head-to-tail crystal packings is determined.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"65 8\",\"pages\":\"1631 - 1640\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-09-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624080146\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624080146","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis and Structure of 4-[(anthracene-9′-ylmethylene)amino]-5-R-2,4-Dihydro-3H-1,2,4-Triazole-3-Thiones
By the condensation of 4-amino-5-R-2,4-dihydro-3H-1,2,4-triazole-3-thiones with anthracene-9- carbaldehyde, respective 4-[(anthracene-9′-ylmethylene)amine)]-5-R-2,4-dihydro-3H-1,2,4-triazole-3-thiones are prepared and structurally characterized by NMR, UV, IR spectroscopies, high-resolution mass spectrometry, and single crystal XRD. The effect of a substituent at position 5 in triazole moieties of azomethines obtained on their head-to-head or head-to-tail crystal packings is determined.
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Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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