Jialin Li, Zhijian Xiao, Jingling Yang* and Mingshan Zhu*,
{"title":"用于去除气态污染物的密闭锰基催化剂:评论","authors":"Jialin Li, Zhijian Xiao, Jingling Yang* and Mingshan Zhu*, ","doi":"10.1021/acsestengg.4c0035510.1021/acsestengg.4c00355","DOIUrl":null,"url":null,"abstract":"<p >Manganese-based materials are widely applied as catalysts for catalytic removal of gaseous pollutants due to their low cost and excellent redox performance. However, existing challenges such as unsatisfactory activity and stability hinder the application of manganese-based catalysts. Confining manganese-based materials into specific regions has the potential to influence intermolecular arrangement and mass diffusion and lower the activation energy barrier, thereby enhancing reaction stability and the catalyst’s activity. In this critical review, we briefly summarize the common reported nanoconfined manganese-based analogues for gaseous pollutant elimination including nitrogen oxides (NO<sub><i>x</i></sub>) and volatile organic compounds (VOCs). Details of the commonly reported hosts for confined catalysts and their impact on catalytic behavior and an in-depth discussion of the related mechanism are included. Through this critical review, we aim to raise the research attention on using confined catalysis as a fundamental guide or even tool to improve the catalytic performance of gaseous pollutant elimination.</p>","PeriodicalId":7008,"journal":{"name":"ACS ES&T engineering","volume":null,"pages":null},"PeriodicalIF":7.4000,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Confined Manganese-Based Catalysts for Gaseous Pollutant Removal: A Critical Review\",\"authors\":\"Jialin Li, Zhijian Xiao, Jingling Yang* and Mingshan Zhu*, \",\"doi\":\"10.1021/acsestengg.4c0035510.1021/acsestengg.4c00355\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Manganese-based materials are widely applied as catalysts for catalytic removal of gaseous pollutants due to their low cost and excellent redox performance. However, existing challenges such as unsatisfactory activity and stability hinder the application of manganese-based catalysts. Confining manganese-based materials into specific regions has the potential to influence intermolecular arrangement and mass diffusion and lower the activation energy barrier, thereby enhancing reaction stability and the catalyst’s activity. In this critical review, we briefly summarize the common reported nanoconfined manganese-based analogues for gaseous pollutant elimination including nitrogen oxides (NO<sub><i>x</i></sub>) and volatile organic compounds (VOCs). Details of the commonly reported hosts for confined catalysts and their impact on catalytic behavior and an in-depth discussion of the related mechanism are included. Through this critical review, we aim to raise the research attention on using confined catalysis as a fundamental guide or even tool to improve the catalytic performance of gaseous pollutant elimination.</p>\",\"PeriodicalId\":7008,\"journal\":{\"name\":\"ACS ES&T engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":7.4000,\"publicationDate\":\"2024-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS ES&T engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsestengg.4c00355\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS ES&T engineering","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsestengg.4c00355","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Confined Manganese-Based Catalysts for Gaseous Pollutant Removal: A Critical Review
Manganese-based materials are widely applied as catalysts for catalytic removal of gaseous pollutants due to their low cost and excellent redox performance. However, existing challenges such as unsatisfactory activity and stability hinder the application of manganese-based catalysts. Confining manganese-based materials into specific regions has the potential to influence intermolecular arrangement and mass diffusion and lower the activation energy barrier, thereby enhancing reaction stability and the catalyst’s activity. In this critical review, we briefly summarize the common reported nanoconfined manganese-based analogues for gaseous pollutant elimination including nitrogen oxides (NOx) and volatile organic compounds (VOCs). Details of the commonly reported hosts for confined catalysts and their impact on catalytic behavior and an in-depth discussion of the related mechanism are included. Through this critical review, we aim to raise the research attention on using confined catalysis as a fundamental guide or even tool to improve the catalytic performance of gaseous pollutant elimination.
期刊介绍:
ACS ES&T Engineering publishes impactful research and review articles across all realms of environmental technology and engineering, employing a rigorous peer-review process. As a specialized journal, it aims to provide an international platform for research and innovation, inviting contributions on materials technologies, processes, data analytics, and engineering systems that can effectively manage, protect, and remediate air, water, and soil quality, as well as treat wastes and recover resources.
The journal encourages research that supports informed decision-making within complex engineered systems and is grounded in mechanistic science and analytics, describing intricate environmental engineering systems. It considers papers presenting novel advancements, spanning from laboratory discovery to field-based application. However, case or demonstration studies lacking significant scientific advancements and technological innovations are not within its scope.
Contributions containing experimental and/or theoretical methods, rooted in engineering principles and integrated with knowledge from other disciplines, are welcomed.