{"title":"光氧化催化烯与喹喔啉酮和氯仿的双官能化反应","authors":"","doi":"10.1016/j.mcat.2024.114546","DOIUrl":null,"url":null,"abstract":"<div><p>A novel visible-light-induced multicomponent reaction of alkene with chloroform and quinoxalinone have been realized <em>via</em> a photocatalytic single electron transfer (SET). This protocol presents an efficient approach for the introduction of chloroalkyl motifs into <em>N</em>-heteroarenes. Meanwhile, this process features good functional group tolerance, and providing the corresponding products in moderate to good yields.</p></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":null,"pages":null},"PeriodicalIF":3.9000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photoredox-catalyzed difunctionalization of alkenes with quinoxalinone and chloroform\",\"authors\":\"\",\"doi\":\"10.1016/j.mcat.2024.114546\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A novel visible-light-induced multicomponent reaction of alkene with chloroform and quinoxalinone have been realized <em>via</em> a photocatalytic single electron transfer (SET). This protocol presents an efficient approach for the introduction of chloroalkyl motifs into <em>N</em>-heteroarenes. Meanwhile, this process features good functional group tolerance, and providing the corresponding products in moderate to good yields.</p></div>\",\"PeriodicalId\":393,\"journal\":{\"name\":\"Molecular Catalysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Molecular Catalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2468823124007284\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molecular Catalysis","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468823124007284","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Photoredox-catalyzed difunctionalization of alkenes with quinoxalinone and chloroform
A novel visible-light-induced multicomponent reaction of alkene with chloroform and quinoxalinone have been realized via a photocatalytic single electron transfer (SET). This protocol presents an efficient approach for the introduction of chloroalkyl motifs into N-heteroarenes. Meanwhile, this process features good functional group tolerance, and providing the corresponding products in moderate to good yields.
期刊介绍：
Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are:
Heterogeneous catalysis including immobilized molecular catalysts
Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis
Photo- and electrochemistry
Theoretical aspects of catalysis analyzed by computational methods
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