{"title":"基于桥接聚氧化金属配体的三种钠配位聚合物的合成、晶体结构和性质","authors":"","doi":"10.1016/j.ica.2024.122380","DOIUrl":null,"url":null,"abstract":"<div><p>The syntheses, crystal structures, spectral characterization, electrochemical, photoredox properties and biological studies of three sodium coordination polymers viz. (ImH)<sub>4</sub>[(µ<sub>2</sub>-HMo<sub>7</sub>O<sub>24</sub>)Na(H<sub>2</sub>O)<sub>8</sub>]∙7H<sub>2</sub>O <strong>1</strong> (Im = Imidazole), [(TEAH)Na<sub>5</sub>(H<sub>2</sub>O)<sub>12</sub>(<em>µ<sub>5</sub></em>-Mo<sub>7</sub>O<sub>24</sub>)] <strong>2</strong> (TEA=triethanolamine) and [Na<sub>2</sub>(PyrH)<sub>2</sub>(<em>µ<sub>2</sub></em>-Mo<sub>8</sub>O<sub>26</sub>)(H<sub>2</sub>O)<sub>7</sub>]∙8H<sub>2</sub>O <strong>3</strong> (Pyr = pyrazole) are reported. The unique Na atom in <strong>1</strong> exhibits ten coordination unlike hexa coordination observed in <strong>2</strong> and <strong>3</strong>. The µ<sub>2</sub>-bridging heptamolybdate (or octamolybdate) anion in <strong>1</strong> (or <strong>3</strong>) links the sodium cations into an infinite chain resulting in a one-dimensional coordination polymer. In <strong>2,</strong> the heptamolybdate anion exhibits an unprecedented <em>µ<sub>5</sub></em>-nonadentate binding resulting in a three- dimensional (3D) structure. Compounds <strong>1</strong>–<strong>3</strong> exhibit characteristic Raman bands. Solar irradiation of <strong>2</strong> results in photodimerization, which is further supported by electrochemical studies. Compounds <strong>1</strong>–<strong>3</strong> exhibit antibacterial activity, with <strong>3</strong> being the most effective against <em>S. Pyogenes</em>, followed by <em>P. aeruginosa</em>, <em>S.typhi</em> and <em>S. aureus</em>. Compound <strong>3</strong> exhibits excellent antidiabetic and anti-inflammatory properties. A comparative study of the binding modes of several heptamolybdates and octamolybdates based compounds is presented.</p></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0020169324004717/pdfft?md5=47e792addf54a098e197e056965c7fa7&pid=1-s2.0-S0020169324004717-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Synthesis, crystal structures and properties of three sodium coordination polymers based on bridging polyoxometalate ligands\",\"authors\":\"\",\"doi\":\"10.1016/j.ica.2024.122380\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The syntheses, crystal structures, spectral characterization, electrochemical, photoredox properties and biological studies of three sodium coordination polymers viz. (ImH)<sub>4</sub>[(µ<sub>2</sub>-HMo<sub>7</sub>O<sub>24</sub>)Na(H<sub>2</sub>O)<sub>8</sub>]∙7H<sub>2</sub>O <strong>1</strong> (Im = Imidazole), [(TEAH)Na<sub>5</sub>(H<sub>2</sub>O)<sub>12</sub>(<em>µ<sub>5</sub></em>-Mo<sub>7</sub>O<sub>24</sub>)] <strong>2</strong> (TEA=triethanolamine) and [Na<sub>2</sub>(PyrH)<sub>2</sub>(<em>µ<sub>2</sub></em>-Mo<sub>8</sub>O<sub>26</sub>)(H<sub>2</sub>O)<sub>7</sub>]∙8H<sub>2</sub>O <strong>3</strong> (Pyr = pyrazole) are reported. The unique Na atom in <strong>1</strong> exhibits ten coordination unlike hexa coordination observed in <strong>2</strong> and <strong>3</strong>. The µ<sub>2</sub>-bridging heptamolybdate (or octamolybdate) anion in <strong>1</strong> (or <strong>3</strong>) links the sodium cations into an infinite chain resulting in a one-dimensional coordination polymer. In <strong>2,</strong> the heptamolybdate anion exhibits an unprecedented <em>µ<sub>5</sub></em>-nonadentate binding resulting in a three- dimensional (3D) structure. Compounds <strong>1</strong>–<strong>3</strong> exhibit characteristic Raman bands. Solar irradiation of <strong>2</strong> results in photodimerization, which is further supported by electrochemical studies. Compounds <strong>1</strong>–<strong>3</strong> exhibit antibacterial activity, with <strong>3</strong> being the most effective against <em>S. Pyogenes</em>, followed by <em>P. aeruginosa</em>, <em>S.typhi</em> and <em>S. aureus</em>. Compound <strong>3</strong> exhibits excellent antidiabetic and anti-inflammatory properties. A comparative study of the binding modes of several heptamolybdates and octamolybdates based compounds is presented.</p></div>\",\"PeriodicalId\":13599,\"journal\":{\"name\":\"Inorganica Chimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0020169324004717/pdfft?md5=47e792addf54a098e197e056965c7fa7&pid=1-s2.0-S0020169324004717-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganica Chimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0020169324004717\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0020169324004717","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis, crystal structures and properties of three sodium coordination polymers based on bridging polyoxometalate ligands
The syntheses, crystal structures, spectral characterization, electrochemical, photoredox properties and biological studies of three sodium coordination polymers viz. (ImH)4[(µ2-HMo7O24)Na(H2O)8]∙7H2O 1 (Im = Imidazole), [(TEAH)Na5(H2O)12(µ5-Mo7O24)] 2 (TEA=triethanolamine) and [Na2(PyrH)2(µ2-Mo8O26)(H2O)7]∙8H2O 3 (Pyr = pyrazole) are reported. The unique Na atom in 1 exhibits ten coordination unlike hexa coordination observed in 2 and 3. The µ2-bridging heptamolybdate (or octamolybdate) anion in 1 (or 3) links the sodium cations into an infinite chain resulting in a one-dimensional coordination polymer. In 2, the heptamolybdate anion exhibits an unprecedented µ5-nonadentate binding resulting in a three- dimensional (3D) structure. Compounds 1–3 exhibit characteristic Raman bands. Solar irradiation of 2 results in photodimerization, which is further supported by electrochemical studies. Compounds 1–3 exhibit antibacterial activity, with 3 being the most effective against S. Pyogenes, followed by P. aeruginosa, S.typhi and S. aureus. Compound 3 exhibits excellent antidiabetic and anti-inflammatory properties. A comparative study of the binding modes of several heptamolybdates and octamolybdates based compounds is presented.
期刊介绍：
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.
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