激光剥离抗侵蚀 TiN 涂层中的热机械耦合效应诱导形貌演变

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-20 DOI:10.1016/j.optlastec.2024.111817
Pengcheng Dou , Guangyu He , Yinghong Li , Zhaolu Zhang , Yan Chai
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引用次数: 0

摘要

激光剥离已成为航空和装甲车辆工业修复抗侵蚀涂层的关键技术。这一过程涉及复杂的热力学相互作用,而对这一过程的探索还很不够。揭示剥离机理的复杂性,尤其是表面形态的演变,对于提高其工业实用性至关重要。本研究利用共聚焦显微镜、扫描电子显微镜和能量色散光谱仪描述了激光对 TiN 防侵蚀涂层的剥离效应。值得注意的是,在能量密度阈值约为 102 J/cm2 时,可观察到脉冲激光诱导出一种独特的流体力学表面形态,以平行的不对称沟槽为标志。这一现象伴随着表面元素的重新分布和氮含量的减少。为了剖析其基本机制,我们开发了结合传热学和流体动力学原理的模拟模型。这些模型显示,TiN 的高温分解和汽化,加上蒸汽反冲压力导致的熔融材料喷射,是剥离过程的核心。此外,不对称沟槽轮廓的形成主要归因于重叠激光光斑的非线性叠加效应。
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Thermo-mechanical coupling effect induced morphology evolution in laser stripping anti-erosion TiN coatings

Laser stripping has emerged as a pivotal technique for repairing anti-erosion coatings in the aviation and armored vehicle industries. This process entails complex thermodynamic interactions that remain incompletely explored. Unraveling the intricacies of the stripping mechanism, especially the evolution of surface morphology, is essential for advancing its industrial utility. This study characterizes the laser stripping effect on TiN anti-erosion coatings using confocal microscopy, scanning electron microscopy, and energy dispersive spectrometer. Notably, at an energy density threshold of approximately 102 J/cm2, pulsed lasers are observed to induce a distinctive hydrodynamic surface morphology, marked by parallel asymmetric grooves. This phenomenon is accompanied by a redistribution of surface elements and a decrease in nitrogen content. To dissect the underlying mechanisms, we have developed simulation models that integrate principles of heat transfer and fluid dynamics. These models reveal that the high-temperature decomposition and vaporization of TiN, coupled with the ejection of molten material due to vapor recoil pressure, are central to the stripping process. Additionally, the formation of asymmetric groove profiles is predominantly attributed to the nonlinear superposition effect from overlapping laser spots.

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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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