{"title":"在 303.15、313.15、323.15 K 和 101.325 kPa 下{氧化甲酯 + 二乙氧基甲烷 + 水}三元体系的液液平衡数据和热力学模型","authors":"Hongyue Guo, Tao Li, Qingsong Li, Zhongtao Li","doi":"10.1007/s10953-024-01398-0","DOIUrl":null,"url":null,"abstract":"<p>The liquid–liquid equilibrium (LLE) of the mesityl oxide + diethoxymethane + water was determined at 303.15, 313.15 and 323.15 K under 101.325 kPa, which was consistent with the Treybal’s type II ternary phase behavior. The distribution coefficients (<i>D</i>) and selectivity coefficients (<i>S</i>) were used to evaluate the extraction ability of mesityl oxide to extract diethoxymethane from water. The experimental data were correlated with the NRTL and UNIQUAC thermodynamic models, and the <i>RMSD</i> values are both less than 0.47%, indicating that the two models can well correlate the experimental data.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Liquid–Liquid Equilibria Data and Thermodynamic Modeling of {Mesityl Oxide + Diethoxymethane + Water} Ternary System at 303.15, 313.15, 323.15 K Under 101.325 kPa\",\"authors\":\"Hongyue Guo, Tao Li, Qingsong Li, Zhongtao Li\",\"doi\":\"10.1007/s10953-024-01398-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The liquid–liquid equilibrium (LLE) of the mesityl oxide + diethoxymethane + water was determined at 303.15, 313.15 and 323.15 K under 101.325 kPa, which was consistent with the Treybal’s type II ternary phase behavior. The distribution coefficients (<i>D</i>) and selectivity coefficients (<i>S</i>) were used to evaluate the extraction ability of mesityl oxide to extract diethoxymethane from water. The experimental data were correlated with the NRTL and UNIQUAC thermodynamic models, and the <i>RMSD</i> values are both less than 0.47%, indicating that the two models can well correlate the experimental data.</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10953-024-01398-0\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10953-024-01398-0","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Liquid–Liquid Equilibria Data and Thermodynamic Modeling of {Mesityl Oxide + Diethoxymethane + Water} Ternary System at 303.15, 313.15, 323.15 K Under 101.325 kPa
The liquid–liquid equilibrium (LLE) of the mesityl oxide + diethoxymethane + water was determined at 303.15, 313.15 and 323.15 K under 101.325 kPa, which was consistent with the Treybal’s type II ternary phase behavior. The distribution coefficients (D) and selectivity coefficients (S) were used to evaluate the extraction ability of mesityl oxide to extract diethoxymethane from water. The experimental data were correlated with the NRTL and UNIQUAC thermodynamic models, and the RMSD values are both less than 0.47%, indicating that the two models can well correlate the experimental data.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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