硝基烯烃加氢和转移加氢的双功能 Fe2O3 催化剂

IF 6 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Materials Chemistry Frontiers Pub Date : 2024-09-20 DOI:10.1039/d4qm00605d
Jinping Zhao, Shixiong Gao, Zihan Feng, Junliang Liu, Yuefang Zhang, Wenxiang Wu, Zinan Zhang, Jiaheng Qin, Kun Liang, Yu Long
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引用次数: 0

摘要

采用简易沉淀法制备的 Fe2O3-200 可同时激活 H2 和等体积 N2H4-H2O,从而还原硝基苯生成苯胺。Fe2O3-200 能有效吸附和活化硝基,促进硝基烯烃的氢化。值得注意的是,N2H4-H2O 的分解依赖于硝基的存在。此外,Fe2O3-200 还具有良好的稳定性和通用性。
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Bifunctional Fe2O3 catalyst for hydrogenation and transfer hydrogenation of nitroarenes
Fe2O3-200 prepared by facile precipitation method could active both H2 and stoichiometric N2H4·H2O to reduce nitrobenzene forming aniline. Fe2O3-200 could efficent adsorb and active nitro group, promoting hydrogenation of nitroarenes. Notably, the decomposed of N2H4·H2O rely on the presence of nitro group. Moreover, Fe2O3-200 exhibits good stability and universality.
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来源期刊
Materials Chemistry Frontiers
Materials Chemistry Frontiers Materials Science-Materials Chemistry
CiteScore
12.00
自引率
2.90%
发文量
313
期刊介绍: Materials Chemistry Frontiers focuses on the synthesis and chemistry of exciting new materials, and the development of improved fabrication techniques. Characterisation and fundamental studies that are of broad appeal are also welcome. This is the ideal home for studies of a significant nature that further the development of organic, inorganic, composite and nano-materials.
期刊最新文献
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