{"title":"氨基官能化 β-二乙酰亚胺配体稳定胚芽烯和亚锡的合成与反应活性","authors":"Tianyi Sun, Cheng Kong, Linlin Wu, Hao Wang","doi":"10.1002/ejic.202400378","DOIUrl":null,"url":null,"abstract":"Amino-functionalized β-diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β-diketiminate stabilized tert-butoxygermylene 3 and tert-butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis-stannylene 5 containing a four-membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X-ray analysis.","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Reactivity of the Amino-Functionalized β-Diketiminate Ligand Stabilized Germylene and Stannylene\",\"authors\":\"Tianyi Sun, Cheng Kong, Linlin Wu, Hao Wang\",\"doi\":\"10.1002/ejic.202400378\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Amino-functionalized β-diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β-diketiminate stabilized tert-butoxygermylene 3 and tert-butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis-stannylene 5 containing a four-membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X-ray analysis.\",\"PeriodicalId\":2,\"journal\":{\"name\":\"ACS Applied Bio Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Bio Materials\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1002/ejic.202400378\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, BIOMATERIALS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Bio Materials","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1002/ejic.202400378","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
Synthesis and Reactivity of the Amino-Functionalized β-Diketiminate Ligand Stabilized Germylene and Stannylene
Amino-functionalized β-diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β-diketiminate stabilized tert-butoxygermylene 3 and tert-butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis-stannylene 5 containing a four-membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X-ray analysis.
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