{"title":"不对称 2,4-二芳基取代和 3-溴-2-(4-溴烷氧基)衍生吡喃香豆素的合成。","authors":"Velu Saravanan , Pin-Hui Lin , Ding-Yah Yang","doi":"10.1039/d4ob01353k","DOIUrl":null,"url":null,"abstract":"<div><div>A series of unsymmetrical 2,4-disubstituted pyranocoumarins and 3-bromo-2-(4-bromoalkoxy)-derived pyranocoumarins were synthesized <em>via</em> the palladium-catalyzed C–H arylation of 4-phenyl-4<em>H</em>,5<em>H</em>-pyrano[3,2-<em>c</em>]chromen-5-ones with aryl iodide and the three-component reaction of 4-phenyl-4<em>H</em>,5<em>H</em>-pyrano[3,2-<em>c</em>]chromen-5-one with bromine and cyclic ether, respectively.</div></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"22 41","pages":"Pages 8310-8316"},"PeriodicalIF":2.7000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of unsymmetrical 2,4-diaryl substituted and 3-bromo-2-(4-bromoalkoxy)-derived pyranocoumarins†\",\"authors\":\"Velu Saravanan , Pin-Hui Lin , Ding-Yah Yang\",\"doi\":\"10.1039/d4ob01353k\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series of unsymmetrical 2,4-disubstituted pyranocoumarins and 3-bromo-2-(4-bromoalkoxy)-derived pyranocoumarins were synthesized <em>via</em> the palladium-catalyzed C–H arylation of 4-phenyl-4<em>H</em>,5<em>H</em>-pyrano[3,2-<em>c</em>]chromen-5-ones with aryl iodide and the three-component reaction of 4-phenyl-4<em>H</em>,5<em>H</em>-pyrano[3,2-<em>c</em>]chromen-5-one with bromine and cyclic ether, respectively.</div></div>\",\"PeriodicalId\":96,\"journal\":{\"name\":\"Organic & Biomolecular Chemistry\",\"volume\":\"22 41\",\"pages\":\"Pages 8310-8316\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic & Biomolecular Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1477052024008425\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052024008425","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Synthesis of unsymmetrical 2,4-diaryl substituted and 3-bromo-2-(4-bromoalkoxy)-derived pyranocoumarins†
A series of unsymmetrical 2,4-disubstituted pyranocoumarins and 3-bromo-2-(4-bromoalkoxy)-derived pyranocoumarins were synthesized via the palladium-catalyzed C–H arylation of 4-phenyl-4H,5H-pyrano[3,2-c]chromen-5-ones with aryl iodide and the three-component reaction of 4-phenyl-4H,5H-pyrano[3,2-c]chromen-5-one with bromine and cyclic ether, respectively.
期刊介绍:
Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.