{"title":"用于合成八元环的可见光诱导过环级联反应","authors":"","doi":"10.1016/j.tetlet.2024.155309","DOIUrl":null,"url":null,"abstract":"<div><div>A visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings is described. The reaction proceeds <em>via</em> [2 + 2]-photocycloaddition, base-promoted elimination, and retro-4π-electrocyclization. It exhibits broad substrate scope and good functional group tolerance.</div></div>","PeriodicalId":438,"journal":{"name":"Tetrahedron Letters","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0040403924004040/pdfft?md5=941608b173ee8fb387c8599daa39a5ee&pid=1-s2.0-S0040403924004040-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings\",\"authors\":\"\",\"doi\":\"10.1016/j.tetlet.2024.155309\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings is described. The reaction proceeds <em>via</em> [2 + 2]-photocycloaddition, base-promoted elimination, and retro-4π-electrocyclization. It exhibits broad substrate scope and good functional group tolerance.</div></div>\",\"PeriodicalId\":438,\"journal\":{\"name\":\"Tetrahedron Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0040403924004040/pdfft?md5=941608b173ee8fb387c8599daa39a5ee&pid=1-s2.0-S0040403924004040-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0040403924004040\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040403924004040","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings
A visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings is described. The reaction proceeds via [2 + 2]-photocycloaddition, base-promoted elimination, and retro-4π-electrocyclization. It exhibits broad substrate scope and good functional group tolerance.
期刊介绍:
Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.