Xu Sun , Gan Zhang , Bo Ye , Wen-Chao Yang , Lei Wang , Xiaoyu Xie , Yicheng Zhang , Jie Liu
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Synthesis of γ-keto sulfones through sulfonylation/acylation of alkenes merging NHC- and photo-catalysis
A three-component coupling of alkenes, sodium sulfinates and acyl imidazoles to access γ-keto sulfones with good functional group tolerance via cooperative N‒heterocyclic carbene (NHC)/photocatalysis is developed. Radical mechanism was proposed for the cascade reaction, revealing that a rare radical/radical cation cross-coupling reaction plays an important role.
期刊介绍：
Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are:
Heterogeneous catalysis including immobilized molecular catalysts
Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis
Photo- and electrochemistry
Theoretical aspects of catalysis analyzed by computational methods
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