从大戟中可持续地合成多元氧化铜纳米颗粒:揭示抗菌和催化潜力

IF 3.9 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-09-26 DOI:10.1016/j.mseb.2024.117718
Shradhanjali Samal , Miraj Patel , Anshika Rohilla , Kirtan Chandodwala , Sonal Thakore
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引用次数: 0

摘要

本研究介绍了以大戟科植物为介质的多用途氧化铜纳米粒子(ET@CuO-NPs)的绿色合成,其抗菌活性得到了增强。利用傅立叶变换红外光谱(FTIR)、拉曼光谱(Raman)、紫外可见光谱(UV-Vis)、扫描电镜(SEM)、HR-TEM、DLS、ZETA电位、XPS和XRD等先进技术对这些植物提取物封端的纳米粒子进行了表征。在 HR-TEM 图像中观察到均匀的棒状形态,大小约为 50 纳米。采用琼脂井扩散法研究了抗菌和抗真菌活性。对革兰氏阴性菌和一种革兰氏阳性菌的抑菌作用分别为 28 毫米和 34 毫米。纳米粒子还通过 DPPH 清除自由基的方法显示出卓越的抗氧化活性。ET@CuO-NPs 的作用范围扩展到催化硝基芳香族化合物还原成相应的氨基衍生物。模型硝基芳香族污染物 4-硝基苯酚的还原可在短短 6 分钟内完成,循环效率高达 8 次。因此,多元 ET@CuO-NPs 具有多种治疗和催化潜力。
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Sustainable synthesis of multifaceted copper oxide nanoparticles from Euphorbia tirucalli: Unveiling antimicrobial and catalytic potential
This work presents Euphorbia tirucalli mediated green synthesis of multi-purpose copper oxide nanoparticles (ET@CuO-NPs) exhibiting enhanced antimicrobial activity. These plant extract capped nanoparticles were characterized using sophisticated techniques such as FTIR, Raman, UV–Vis, SEM, HR-TEM, DLS, zeta potential, XPS and XRD. A uniform rod-shaped morphology was observed in HR-TEM images with size around 50 nm. Antibacterial and antifungal activity was investigated by agar well diffusion method. The bactericidal action was confirmed by zone of inhibition of 28 mm and 34 mm respectively against gram-negative and a gram-positive bacterium. The nanoparticles also show excellent antioxidant activity via free radical scavenging by DPPH. The scope of ET@CuO-NPs was extended to catalytic reduction of nitroaromatic compounds into their corresponding amino derivatives. The reduction of 4-nitrophenol, a model nitroaromatic pollutant could be completed within just 6 min with a recycling efficiency of 8 cycles. Thus, the multifaceted ET@CuO-NPs exhibited diverse therapeutic and catalytic potential.
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来源期刊
CiteScore
5.60
自引率
2.80%
发文量
481
审稿时长
3.5 months
期刊介绍: The journal provides an international medium for the publication of theoretical and experimental studies and reviews related to the electronic, electrochemical, ionic, magnetic, optical, and biosensing properties of solid state materials in bulk, thin film and particulate forms. Papers dealing with synthesis, processing, characterization, structure, physical properties and computational aspects of nano-crystalline, crystalline, amorphous and glassy forms of ceramics, semiconductors, layered insertion compounds, low-dimensional compounds and systems, fast-ion conductors, polymers and dielectrics are viewed as suitable for publication. Articles focused on nano-structured aspects of these advanced solid-state materials will also be considered suitable.
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