{"title":"掺杂 Tb3+ 的 K3Y(BO2)6 荧光的高温光致发光依赖性和能量迁移","authors":"","doi":"10.1016/j.apradiso.2024.111529","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigates the structural and photoluminescence (PL) characteristics of Tb<sup>3+</sup>-incorporated K<sub>3</sub>Y(BO<sub>2</sub>)<sub>6</sub> (KYBO) phosphors synthesized via a microwave-assisted sol-gel technique. X-ray diffraction (XRD) and Rietveld refinement confirmed the formation of a pure hexagonal phase, with lattice expansion due to Tb³⁺ doping. PL studies revealed strong green emissions centered at 541 nm, attributed to the ⁵D₄ → ⁷F₅ transitions of Tb³⁺ ions, with the highest intensity observed at 5 wt% Tb³⁺. A decrease in emission was observed at higher concentrations due to concentration quenching. Temperature-dependent PL measurements revealed reverse thermal quenching enhancing PL intensity. Chromaticity analysis based on CIE 1931 coordinates showed stable green emission across all concentrations, with a maximum color purity of 89.74% observed for the KYBO:3 wt% Tb³⁺ sample. The results, along with reverse thermal quenching behavior observed between 470K and 550K, suggest that these phosphors exhibit excellent potential for lighting and display technologies.</div></div>","PeriodicalId":8096,"journal":{"name":"Applied Radiation and Isotopes","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High temperature photoluminescence dependence and energy migration of Tb3+-Incorporated K3Y(BO2)6 phosphors\",\"authors\":\"\",\"doi\":\"10.1016/j.apradiso.2024.111529\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study investigates the structural and photoluminescence (PL) characteristics of Tb<sup>3+</sup>-incorporated K<sub>3</sub>Y(BO<sub>2</sub>)<sub>6</sub> (KYBO) phosphors synthesized via a microwave-assisted sol-gel technique. X-ray diffraction (XRD) and Rietveld refinement confirmed the formation of a pure hexagonal phase, with lattice expansion due to Tb³⁺ doping. PL studies revealed strong green emissions centered at 541 nm, attributed to the ⁵D₄ → ⁷F₅ transitions of Tb³⁺ ions, with the highest intensity observed at 5 wt% Tb³⁺. A decrease in emission was observed at higher concentrations due to concentration quenching. Temperature-dependent PL measurements revealed reverse thermal quenching enhancing PL intensity. Chromaticity analysis based on CIE 1931 coordinates showed stable green emission across all concentrations, with a maximum color purity of 89.74% observed for the KYBO:3 wt% Tb³⁺ sample. The results, along with reverse thermal quenching behavior observed between 470K and 550K, suggest that these phosphors exhibit excellent potential for lighting and display technologies.</div></div>\",\"PeriodicalId\":8096,\"journal\":{\"name\":\"Applied Radiation and Isotopes\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2024-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Radiation and Isotopes\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0969804324003579\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Radiation and Isotopes","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0969804324003579","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
High temperature photoluminescence dependence and energy migration of Tb3+-Incorporated K3Y(BO2)6 phosphors
This study investigates the structural and photoluminescence (PL) characteristics of Tb3+-incorporated K3Y(BO2)6 (KYBO) phosphors synthesized via a microwave-assisted sol-gel technique. X-ray diffraction (XRD) and Rietveld refinement confirmed the formation of a pure hexagonal phase, with lattice expansion due to Tb³⁺ doping. PL studies revealed strong green emissions centered at 541 nm, attributed to the ⁵D₄ → ⁷F₅ transitions of Tb³⁺ ions, with the highest intensity observed at 5 wt% Tb³⁺. A decrease in emission was observed at higher concentrations due to concentration quenching. Temperature-dependent PL measurements revealed reverse thermal quenching enhancing PL intensity. Chromaticity analysis based on CIE 1931 coordinates showed stable green emission across all concentrations, with a maximum color purity of 89.74% observed for the KYBO:3 wt% Tb³⁺ sample. The results, along with reverse thermal quenching behavior observed between 470K and 550K, suggest that these phosphors exhibit excellent potential for lighting and display technologies.
期刊介绍：
Applied Radiation and Isotopes provides a high quality medium for the publication of substantial, original and scientific and technological papers on the development and peaceful application of nuclear, radiation and radionuclide techniques in chemistry, physics, biochemistry, biology, medicine, security, engineering and in the earth, planetary and environmental sciences, all including dosimetry. Nuclear techniques are defined in the broadest sense and both experimental and theoretical papers are welcome. They include the development and use of α- and β-particles, X-rays and γ-rays, neutrons and other nuclear particles and radiations from all sources, including radionuclides, synchrotron sources, cyclotrons and reactors and from the natural environment.
The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria.
Papers dealing with radiation processing, i.e., where radiation is used to bring about a biological, chemical or physical change in a material, should be directed to our sister journal Radiation Physics and Chemistry.
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