{"title":"从多种底物合成烯烃的综合光化学战略","authors":"","doi":"10.1038/s41557-024-01643-5","DOIUrl":null,"url":null,"abstract":"Despite advances, a general olefination strategy for the direct conversion of carboxylic acids, alcohols and alkanes into alkenes remains challenging owing to their inherent differences in reactivity. Now, a one-pot photochemical method comprising a Giese addition followed by a Norrish type-II fragmentation enables the on-demand production of alkenes from diverse substrates.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"16 11","pages":"1751-1752"},"PeriodicalIF":19.2000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Integrated photochemical strategy for alkene synthesis from diverse substrates\",\"authors\":\"\",\"doi\":\"10.1038/s41557-024-01643-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Despite advances, a general olefination strategy for the direct conversion of carboxylic acids, alcohols and alkanes into alkenes remains challenging owing to their inherent differences in reactivity. Now, a one-pot photochemical method comprising a Giese addition followed by a Norrish type-II fragmentation enables the on-demand production of alkenes from diverse substrates.\",\"PeriodicalId\":18909,\"journal\":{\"name\":\"Nature chemistry\",\"volume\":\"16 11\",\"pages\":\"1751-1752\"},\"PeriodicalIF\":19.2000,\"publicationDate\":\"2024-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.nature.com/articles/s41557-024-01643-5\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.nature.com/articles/s41557-024-01643-5","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
尽管取得了一些进展，但由于羧酸、醇和烷烃的固有反应性不同，将它们直接转化为烯的通用烯化策略仍具有挑战性。现在，一种由 Giese 加成和 Norrish II 型破碎组成的单锅光化学方法可以按需从不同的底物中生产烯烃。
Integrated photochemical strategy for alkene synthesis from diverse substrates
Despite advances, a general olefination strategy for the direct conversion of carboxylic acids, alcohols and alkanes into alkenes remains challenging owing to their inherent differences in reactivity. Now, a one-pot photochemical method comprising a Giese addition followed by a Norrish type-II fragmentation enables the on-demand production of alkenes from diverse substrates.
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