{"title":"基于功能化离子液体的高灵敏度荧光探针,用于及时检测食品中的痕量 Hg2+ 和 CH3Hg+","authors":"","doi":"10.1016/j.foodchem.2024.141343","DOIUrl":null,"url":null,"abstract":"<div><div>A novel fluorescent probe was fabricated using fluorescein-based ionic liquids (ILs) to effectively achieve rapid and accurate detection of Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> in food. A probe developed by addition of modified fluorescein into the functionalised ILs presented a promising sensitivity toward Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> at concentrations of 0.4 and 60 nM, respectively. In addition, the novel probe could achieve visual and timely detection of Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> by the naked eyes at concentrations of 0.1 and 1 μM, respectively. The probe could also overcome the interference of potential ions and common organic ligands and detect Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> in real food samples, such as green tea and liquor. The probe could be converted into a paper-based sensor to visually detect Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> at levels as low as 10 nM.</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":null,"pages":null},"PeriodicalIF":8.5000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A highly sensitive fluorescent probe based on functionalised ionic liquids for timely detection of trace Hg2+ and CH3Hg+ in food\",\"authors\":\"\",\"doi\":\"10.1016/j.foodchem.2024.141343\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A novel fluorescent probe was fabricated using fluorescein-based ionic liquids (ILs) to effectively achieve rapid and accurate detection of Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> in food. A probe developed by addition of modified fluorescein into the functionalised ILs presented a promising sensitivity toward Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> at concentrations of 0.4 and 60 nM, respectively. In addition, the novel probe could achieve visual and timely detection of Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> by the naked eyes at concentrations of 0.1 and 1 μM, respectively. The probe could also overcome the interference of potential ions and common organic ligands and detect Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> in real food samples, such as green tea and liquor. The probe could be converted into a paper-based sensor to visually detect Hg<sup>2+</sup> and CH<sub>3</sub>Hg<sup>+</sup> at levels as low as 10 nM.</div></div>\",\"PeriodicalId\":318,\"journal\":{\"name\":\"Food Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.5000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Food Chemistry\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0308814624029935\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Food Chemistry","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0308814624029935","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
A highly sensitive fluorescent probe based on functionalised ionic liquids for timely detection of trace Hg2+ and CH3Hg+ in food
A novel fluorescent probe was fabricated using fluorescein-based ionic liquids (ILs) to effectively achieve rapid and accurate detection of Hg2+ and CH3Hg+ in food. A probe developed by addition of modified fluorescein into the functionalised ILs presented a promising sensitivity toward Hg2+ and CH3Hg+ at concentrations of 0.4 and 60 nM, respectively. In addition, the novel probe could achieve visual and timely detection of Hg2+ and CH3Hg+ by the naked eyes at concentrations of 0.1 and 1 μM, respectively. The probe could also overcome the interference of potential ions and common organic ligands and detect Hg2+ and CH3Hg+ in real food samples, such as green tea and liquor. The probe could be converted into a paper-based sensor to visually detect Hg2+ and CH3Hg+ at levels as low as 10 nM.
期刊介绍:
Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.