Cu(I)-Catalyzed Highly Regioselective C-H Amidation of Quinoline N-Oxides with Dioxazolones（Cu(I)催化喹啉 N-氧化物与二噁唑酮的高区域选择性 C-H 酰胺化反应

IF 5.4 3区材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-30 DOI:10.1021/acs.orglett.4c03118

Zhiqiang Ren, Tianhui Feng, Tianli Gao, Bo Han, Ruili Guo, Haojie Ma, Ji-Jiang Wang, Yuqi Zhang

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引用次数: 0

摘要

据报道，该研究利用二恶唑酮与喹啉 N-氧化物，在 Cu(I)- 催化下高区域选择性合成了 2-乙酰胺喹啉 N-氧化物。该反应具有温和的反应条件和良好的官能团相容性。此外，加入盐酸可促进铜络合物的分解，有利于后处理。

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Cu(I)-Catalyzed Highly Regioselective C–H Amidation of Quinoline N-Oxides with Dioxazolones

A Cu(I)-catalyzed highly regioselective synthesis of 2-acetamidequinoline N-oxides using dioxazolones with quinoline N-oxides has been reported. The reaction possesses mild reaction conditions and excellent functional group compatibility. Furthermore, the addition of hydrochloric acid promotes the decomposition of copper complexes, which is beneficial for postprocessing.

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来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.