将氮化铀燃料能力纳入 ENIGMA 燃料性能代码:模型开发与验证

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-30 DOI:10.1016/j.nucengdes.2024.113604
Aiden Peakman , Glyn Rossiter
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引用次数: 0

摘要

二氧化铀(UO2)是核反应堆的主要燃料形式,但由于其铀密度适中,导热性较低,因此人们开始探索替代材料。氮化铀(UN)具有更高的铀密度和导热性,已成为各种反应堆的理想候选材料。本文详细介绍了在 ENIGMA 燃料性能代码中为轻水反应堆 (LWR) 应用开发和实施 UN 燃料功能的情况。ENIGMA 中的新 UN 功能包括室温理论密度、热导率、比热容、焓、热膨胀应变、杨氏模量、泊松比、热蠕变应变率、辐照蠕变应变率和发射率的相关性。此外,该模型还包括致密化、固体裂变产物膨胀、裂变气体气泡膨胀和裂变气体释放模型,以及用于确定弹丸径向功率曲线和氦气生成的改进型雷达模型。利用日本 JOYO 快堆的 L414 栓辐照数据对联合国模型进行了验证。计划利用 JOYO 和法国 Siloé 热反应堆的数据集开展进一步验证工作。论文还概述了未来的工作领域,以解决实验数据缺口并提高模型精度,从而涵盖更广泛的包壳材料、制造参数(包括孔隙率体积分数)和运行条件(包括燃料温度和燃耗)。尽管工作重点是低浓铀浓缩反应堆的应用,但所概述的工作支持在各种反应堆系统中使用联合国燃料。
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Incorporation of uranium nitride fuel capability into the ENIGMA fuel performance code: Model development and validation
Uranium dioxide (UO2) is the primary fuel form for nuclear reactors but its moderate uranium density and low thermal conductivity have prompted the exploration of alternative materials. Uranium nitride (UN) has emerged as a promising candidate for a variety of reactors, offering higher uranium density and thermal conductivity. This paper details the development and implementation of UN fuel capabilities within the ENIGMA fuel performance code for Light Water Reactor (LWR) applications. The new UN capability in ENIGMA includes correlations for theoretical density at room temperature, thermal conductivity, specific heat capacity, enthalpy, thermal expansion strain, Young’s modulus, Poisson’s ratio, thermal creep strain rate, irradiation creep strain rate and emissivity. Additionally, it incorporates models for densification, solid fission product swelling, fission gas bubble swelling, and fission gas release, along with a modified RADAR model for determining the pellet radial power profile and helium generation. Validation of the UN model was conducted using data from the L414 pin irradiation in the JOYO fast reactor in Japan. Further validation efforts are planned using datasets from JOYO and the Siloé thermal reactor in France. The paper also outlines areas of future work to address experimental data gaps and enhance model accuracy to cover a broader range of cladding materials, manufacturing parameters (including porosity volume fraction) and operating conditions (including fuel temperatures and burnups). Although focused on LWR applications, the work outlined supports the use of UN fuel across various reactor systems.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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