评估碘异噁唑鎓(III)盐的卤素键强度。

IF 2.2 4区 化学 Q2 CHEMISTRY, ORGANIC Beilstein Journal of Organic Chemistry Pub Date : 2024-09-23 eCollection Date: 2024-01-01 DOI:10.3762/bjoc.20.204
Dominik L Reinhard, Anna Schmidt, Marc Sons, Julian Wolf, Elric Engelage, Stefan M Huber
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引用次数: 0

摘要

近年来,二碘鎓(III)盐已被确定为强大的卤素键供体。在此,我们为这一类化合物开发了一种新的结构模式:碘异噁唑鎓盐,其环状五元碘核心与异噁唑环融合。合成了这一类化合物的衍生物,并通过 X 射线晶体学对其固态进行了研究。最后,在金催化丙炔酰胺环化的溶液中,对其作为卤素键活化剂的潜力进行了基准测试。
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Evaluating the halogen bonding strength of a iodoloisoxazolium(III) salt.

Diaryliodonium(III) salts have been established as powerful halogen-bond donors in recent years. Herein, a new structural motif for this compound class was developed: iodoloisoxazolium salts, bearing a cyclic five-membered iodolium core fused with an isoxazole ring. A derivative of this class was synthesized and investigated in the solid state by X-ray crystallography. Finally, the potential as halogen-bonding activator was benchmarked in solution in the gold-catalyzed cyclization of a propargyl amide.

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来源期刊
CiteScore
4.90
自引率
3.70%
发文量
167
审稿时长
1.4 months
期刊介绍: The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.
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