Fatima Setifi , Zouaoui Setifi , David K. Geiger , Mohammed Hadi Al-Douh , Abderezak Addala
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引用次数: 0
摘要
标题配位聚合物 [Co(N3)2(C9H8N2)] n 是通过溶解热合成的。CoII 原子与一个双阳8-氨基喹啉配体和四个叠氮配体呈扭曲的八面体[CoN6]配位几何结构。桥接的叠氮配体导致链沿着 [100] 延伸。N-H⋯N 氢键将这些链连接起来，形成与 (002) 平行的片状延伸结构。
[Co(C9H8N2)(N3)2]n exhibits a distorted octahedral coordination geometry. Bridging azide ligands result in chains along [100].
The title coordination polymer, [Co(N3)2(C9H8N2)]n, was synthesized solvothermally. The CoII atom exhibits a distorted octahedral [CoN6] coordination geometry with a bidentate 8-aminoquinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N—H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).
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