Fatima Setifi , Zouaoui Setifi , Thang Pham Chien , Mohammad Hadi Al-Douh , Abderezak Addala
{"title":"二-μ-己二胺-κ4 O 1,O 1':O 6,O 6'-双-[(2,2'-二-吡啶基-胺-κ2 N,N')锌(II)]三水合物。","authors":"Fatima Setifi , Zouaoui Setifi , Thang Pham Chien , Mohammad Hadi Al-Douh , Abderezak Addala","doi":"10.1107/S2414314624009064","DOIUrl":null,"url":null,"abstract":"<div><div>The title dinuclear and centrosymmetric complex molecule exhibits a highly distorted octahedral O<sub>4</sub>N<sub>2</sub> coordination set about the central zinc(II) atom.</div></div><div><div>The title compound, [Zn<sub>2</sub>(C<sub>6</sub>H<sub>8</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>9</sub>N<sub>3</sub>)<sub>2</sub>]·3H<sub>2</sub>O or {Zn<sub>2</sub>[(C<sub>5</sub>H<sub>4</sub>N)<sub>2</sub>NH]<sub>2</sub>[μ-(CH<sub>2</sub>)<sub>4</sub>(COO)<sub>2</sub>]<sub>2</sub>}·3H<sub>2</sub>O, was separated from the solvothermal reaction of zinc(II) sulfate heptahydrate, 2,2′-dipyridylamine and sodium adipate. The dinuclear metal complex has a centrosymmetric structure, with the Zn<sup>II</sup> atom adopting a highly distorted octahedral coordination sphere composed of four oxygen atoms from bridging adipato ligands and two pyridine nitrogen atoms. In the crystal, the title compound aggregates into a tri-periodic supramolecular structure through intermolecular hydrogen-bonding networks of the form O—H⋯O and N—H⋯O.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (235KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451035/pdf/","citationCount":"0","resultStr":"{\"title\":\"Di-μ-adipato-κ4O1,O1′:O6,O6′-bis[(2,2′-dipyridylamine-κ2N,N′)zinc(II)] trihydrate\",\"authors\":\"Fatima Setifi , Zouaoui Setifi , Thang Pham Chien , Mohammad Hadi Al-Douh , Abderezak Addala\",\"doi\":\"10.1107/S2414314624009064\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The title dinuclear and centrosymmetric complex molecule exhibits a highly distorted octahedral O<sub>4</sub>N<sub>2</sub> coordination set about the central zinc(II) atom.</div></div><div><div>The title compound, [Zn<sub>2</sub>(C<sub>6</sub>H<sub>8</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>9</sub>N<sub>3</sub>)<sub>2</sub>]·3H<sub>2</sub>O or {Zn<sub>2</sub>[(C<sub>5</sub>H<sub>4</sub>N)<sub>2</sub>NH]<sub>2</sub>[μ-(CH<sub>2</sub>)<sub>4</sub>(COO)<sub>2</sub>]<sub>2</sub>}·3H<sub>2</sub>O, was separated from the solvothermal reaction of zinc(II) sulfate heptahydrate, 2,2′-dipyridylamine and sodium adipate. The dinuclear metal complex has a centrosymmetric structure, with the Zn<sup>II</sup> atom adopting a highly distorted octahedral coordination sphere composed of four oxygen atoms from bridging adipato ligands and two pyridine nitrogen atoms. In the crystal, the title compound aggregates into a tri-periodic supramolecular structure through intermolecular hydrogen-bonding networks of the form O—H⋯O and N—H⋯O.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (235KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451035/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000865\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000865","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The title dinuclear and centrosymmetric complex molecule exhibits a highly distorted octahedral O4N2 coordination set about the central zinc(II) atom.
The title compound, [Zn2(C6H8O4)2(C10H9N3)2]·3H2O or {Zn2[(C5H4N)2NH]2[μ-(CH2)4(COO)2]2}·3H2O, was separated from the solvothermal reaction of zinc(II) sulfate heptahydrate, 2,2′-dipyridylamine and sodium adipate. The dinuclear metal complex has a centrosymmetric structure, with the ZnII atom adopting a highly distorted octahedral coordination sphere composed of four oxygen atoms from bridging adipato ligands and two pyridine nitrogen atoms. In the crystal, the title compound aggregates into a tri-periodic supramolecular structure through intermolecular hydrogen-bonding networks of the form O—H⋯O and N—H⋯O.
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