磁感应加热驱动快速冷启动氨分解制氢

IF 14.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Journal of the American Chemical Society Pub Date : 2024-10-09 DOI:10.1021/jacs.4c10851
Ruiqi Zhang, Xingwu Liu, Ningning Song, Jiahao He, Zeyan Cen, Chengyu Li, Maolin Wang, Haoyi Tang, Wei Liu, Xiao Ren, Ding Ma
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引用次数: 0

摘要

氨作为氢载体的优势促使人们提出了通过氨分解现场制氢的建议。氨分解的快速冷启动对于氨动力汽车等应用至关重要,但传统的加热方法因氨的分解温度过高而面临挑战。在这项研究中,我们使用 Co 纳米粒子催化剂通过磁感应加热成功实现了氨分解的快速冷启动,并展示了优异的催化性能和稳定性。磁感应加热驱动的氨分解系统与氢燃料电池相结合,通过以气瓶中 75% H2-25% N2 为对照的对比实验,证明了该系统能够在 10 秒内实现氨分解的冷启动。这项研究加深了对滞后加热催化的理解,促进了氨作为氢载体在能源工业中快速制氢的实际应用。
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Magnetic Induction Heating-Driven Rapid Cold Start of Ammonia Decomposition for Hydrogen Production
The advantages of ammonia as a hydrogen carrier have led to proposals for on-site hydrogen production through its decomposition. Rapid cold start of ammonia decomposition is crucial for applications such as ammonia-powered vehicles, but conventional heating methods are challenged by the high decomposition temperature of ammonia. In this study, we successfully achieved the rapid cold start of ammonia decomposition using Co nanoparticle catalysts driven by magnetic induction heating, demonstrating excellent catalytic performance and stability. The magnetic induction heating-driven ammonia decomposition system was integrated with a hydrogen fuel cell, proving its ability to achieve the cold start of ammonia decomposition within 10 s, as demonstrated by comparative experiments using 75% H2-25% N2 from a gas cylinder as the control. This study provides a deeper understanding of hysteresis heating catalysis, promoting the practical use of ammonia as a hydrogen carrier for rapid hydrogen production in the energy industry.
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来源期刊
CiteScore
24.40
自引率
6.00%
发文量
2398
审稿时长
1.6 months
期刊介绍: The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.
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