基于 VMD-SG 辅助光学噪声抑制的 OAIC-HC 模式近红外双量程甲烷传感器。

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Analytical Chemistry Pub Date : 2024-10-22 Epub Date: 2024-10-09 DOI:10.1021/acs.analchem.4c03771
Guolin Li, Siyu Zhang, Yajing Liu, Enting Dong, Lupeng Jia, Fuli Zhao, Yingjie Zhao, Longju Li, Haoran Yuan, Guangzhao Cui, Ruixiang Sun
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引用次数: 0

摘要

基于可调谐二极管激光吸收光谱和离轴集成腔输出光谱,利用 CH4 气体分子在 1653.7 nm 处的泛音吸收带,构建了一种双量程甲烷混合传感器。同时利用有效吸收路径分别为 11 米和 405 米的离轴集成腔和赫里奥特池,通过 VMD 将接收到的两个光电信号分解为不同的频率分量,然后经过 SG 滤波后进行重构。应用全局优化算法 DA-ELM 进行 CH4 浓度反演,相关系数 R2 高达 0.9995。通过长期稳定性验证,仪器在 1 ppm 时的标准偏差为 27 ppb。经过 Allan-Werle 偏差分析,在 138 秒积分时间内,传感器的检测限为 2.298 ppb。利用自主研发的传感器,实现了双量程痕量甲烷气体的检测,使痕量甲烷气体的动态检测范围达到 400 ppb 至 1000 ppm。该传感器实现了双量程甲烷痕量检测,可主动控制甲烷排放,改善环境质量,同时兼顾减少生产事故的安全效益。
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Near-Infrared Dual-Range Methane Sensor Using the OAIC-HC Mode Based on VMD-SG-Assisted Optical Noise Suppression.

Based on tunable diode laser absorption spectroscopy and off-axis integrated cavity output spectroscopy, a dual-range methane hybrid sensor was constructed utilizing the overtone absorption band of CH4 gas molecules at 1653.7 nm. By simultaneously utilizing an off-axis integrated cavity and Herriott cell with an effective absorption path of 11 and 405 m, respectively, the two received photoelectric signals are decomposed into different frequency components by VMD and then reconstructed after SG filtering. Applying the global optimization algorithm DA-ELM to CH4 concentration inversion, the correlation coefficient R2 is as high as 0.9995. Through long-term stability verification, the instrument's standard deviation at 1 ppm is 27 ppb. After Allan-Werle deviation analysis, the sensor's limit of detection is 2.298 ppb at an integration time of 138 s. Using the self-developed sensor, the detection of dual-range trace CH4 gas is achieved, enabling a dynamic detection range of trace CH4 gas ranging from 400 ppb to 1000 ppm. The sensor realizes dual-range methane trace detection and actively controls methane emissions to improve environmental quality while taking into account the safety benefits of reducing production accidents.

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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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