铜（II）喹喔啉咪唑鎓络合物在催化氧化苄醇和杂环醇中的作用。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-10-02 Epub Date: 2024-10-01 DOI:10.1039/d4ob01081g

Xiaoyu Huo , Mariano Guagliardo , Anne E. V. Gorden

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引用次数: 0

摘要

在先前研究的基础上，利用缩合反应制备了一种新型喹喔啉醇铜(II)络合物。以叔丁基过氧化氢（TBHP）为氧化剂，将喹喔啉铜(II)络合物用作催化剂，结果表明苄醇和杂环醇可以高效地转化为相应的醛。在很短的反应时间内就能获得极高的产率（高达 99%），而且对官能团具有很强的耐受性。

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Copper(ii) quinoxolinol imidazolium complexes in catalytic oxidation of benzylic and heterocyclic alcohols†

A novel copper(ii) quinoxolinol complex has been prepared using a condensation reaction based on previous studies. The copper(ii) quinoxolinol salen complex has been applied as a catalyst using tert-butyl hydroperoxide (TBHP) as the oxidant, demonstrating that benzylic and heterocyclic alcohols can be converted efficiently to the corresponding aldehydes. Excellent yields can be achieved (up to 99%) within a short reaction time and with great tolerance for functional groups.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.