铜（II）喹喔啉咪唑鎓络合物在催化氧化苄醇和杂环醇中的作用。

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-10-08 DOI:10.1039/d4ob01081g

Xiaoyu Huo, Mariano Guagliardo, Anne E V Gorden

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引用次数: 0

摘要

在先前研究的基础上，利用缩合反应制备了一种新型喹喔啉醇铜(II)络合物。以叔丁基过氧化氢（TBHP）为氧化剂，将喹喔啉铜(II)络合物用作催化剂，结果表明苄醇和杂环醇可以高效地转化为相应的醛。在很短的反应时间内就能获得极高的产率（高达 99%），而且对官能团具有很强的耐受性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Copper(II) quinoxolinol imidazolium complexes in catalytic oxidation of benzylic and heterocyclic alcohols.

A novel copper(II) quinoxolinol complex has been prepared using a condensation reaction based on previous studies. The copper(II) quinoxolinol salen complex has been applied as a catalyst using tert-butyl hydroperoxide (TBHP) as the oxidant, demonstrating that benzylic and heterocyclic alcohols can be converted efficiently to the corresponding aldehydes. Excellent yields can be achieved (up to 99%) within a short reaction time and with great tolerance for functional groups.

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