Bismuthene for novel anode material of Magnesium/Zinc ion batteries with high capacity and stability: A DFT calculation

In our research, we utilize density functional theory (DFT) to explore the properties of Magnesium and Zinc atoms adsorbed on bismuthene. Our findings reveal that the most favorable adsorption site for Mg and Zn atoms on bismuthene is the hollow site. The results indicate that Mg and Zn adsorption on the Bi surface results in significantly high conductivity, with notable adsorption energies of -3.38 eV for Mg and -3.91 eV for Zn. The bismuthene structure can adsorb 9 Mg and 18 Zn atoms with negative average adsorption energy. These findings suggest excellent stability of bismuthene during the adsorption of Magnesium and Zinc. Notably, we propose theoretical storage capacities of 2308 mAh/g for Magnesium-ion batteries (MgIBs) and 4616 mAh/g for Zinc-ion batteries (ZnIBs), while maintaining structural stability during the adsorption of these metal ions. The observed average open-circuit voltages for bismuthene are 0.01 V for Mg and 0.03 V for Zn, with the material retaining its metallic properties throughout the adsorption process. Furthermore, the calculated diffusion barriers for Mg and Zn are 0.1 eV and 0.21 eV, respectively. Our findings in storage capacity, diffusion energies, and low OCV surpass those of most studied two-dimensional materials, positioning bismuthene as a promising anode material for metal-ion rechargeable batteries.