基于异策聚丙烯和高压聚乙烯的含镍纳米复合材料

IF 0.5 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Inorganic Materials: Applied Research Pub Date : 2024-10-09 DOI:10.1134/S2075113324700989
N. I. Kurbanova, S. K. Ragimova, T. M. Guliyeva
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引用次数: 0

摘要

摘要--研究了用机械化学方法获得的高压聚乙烯(PE)聚合物基体稳定的含氧化镍纳米粒子(NPs)的纳米填料(NF)添加剂对基于异方性聚丙烯(PP)和高压聚乙烯(PE)的含金属纳米复合材料的结构和性能特性的影响。研究采用了差热分析 (DTA)、X 射线衍射 (XRD) 和扫描电子显微镜 (SEM)。研究发现,获得的纳米复合材料的强度、变形和流变参数以及热氧化稳定性都有所提高。这显然与 PE 基体中的含镍纳米粒子与 PP/PE 聚合物成分的界面相互作用的协同效应有关。研究表明,基于 PP/PE/NF 的纳米复合材料既可以用压制法加工,也可以用注射成型法和挤出法加工,从而扩大了其应用范围。
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Nickel-Containing Nanocomposites Based on Isotactic Polypropylene and High-Pressure Polyethylene

Abstract—The effect of nanofiller (NF) additives containing nickel oxide nanoparticles (NPs) stabilized by a polymer matrix of high-pressure polyethylene (PE) obtained by the mechanochemical method on the peculiarities of the structure and properties of metal-containing nanocomposites based on isotactic polypropylene (PP) and high-pressure polyethylene (PE) is studied. Differential thermal analysis (DTA), X-ray diffraction (XRD), and scanning electron microscopy (SEM) are used. Improvement of the strength, deformation, and rheological parameters as well as thermo-oxidative stability of the obtained nanocomposites is found. This is apparently associated with the synergistic effect of the interfacial interaction of nickel-containing nanoparticles in the PE matrix with the components of the PP/PE polymer composition. It is shown that nanocomposites based on PP/PE/NF can be processed by both the method of pressing and the methods of injection molding and extrusion, which expands the scope of their application.

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来源期刊
Inorganic Materials: Applied Research
Inorganic Materials: Applied Research Engineering-Engineering (all)
CiteScore
0.90
自引率
0.00%
发文量
199
期刊介绍: Inorganic Materials: Applied Research  contains translations of research articles devoted to applied aspects of inorganic materials. Best articles are selected from four Russian periodicals: Materialovedenie, Perspektivnye Materialy, Fizika i Khimiya Obrabotki Materialov, and Voprosy Materialovedeniya  and translated into English. The journal reports recent achievements in materials science: physical and chemical bases of materials science; effects of synergism in composite materials; computer simulations; creation of new materials (including carbon-based materials and ceramics, semiconductors, superconductors, composite materials, polymers, materials for nuclear engineering, materials for aircraft and space engineering, materials for quantum electronics, materials for electronics and optoelectronics, materials for nuclear and thermonuclear power engineering, radiation-hardened materials, materials for use in medicine, etc.); analytical techniques; structure–property relationships; nanostructures and nanotechnologies; advanced technologies; use of hydrogen in structural materials; and economic and environmental issues. The journal also considers engineering issues of materials processing with plasma, high-gradient crystallization, laser technology, and ultrasonic technology. Currently the journal does not accept direct submissions, but submissions to one of the source journals is possible.
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