从三相点到 1000 K 和压力高达 2200 MPa 的氮粘度参考相关性

IF 2.5 4区 工程技术 Q3 CHEMISTRY, PHYSICAL International Journal of Thermophysics Pub Date : 2024-10-10 DOI:10.1007/s10765-024-03440-1
Marcia L. Huber, Richard A. Perkins, Eric W. Lemmon
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引用次数: 0

摘要

我们根据经过严格评估的实验数据和非线性计算,提出了氮气粘度的新的广泛相关性。该相关性设计用于现有状态方程中的密度,其有效值从三相点到 1000 K,压力高达 2200 MPa。粘度的估计不确定性(95% 置信度)因温度和压力而异,室温附近稀释气体范围的不确定性最低为 0.2%,饱和至 34 兆帕压力下液相的不确定性为 4%,压力超过 650 兆帕的超临界区域的不确定性最高为 8%。提供了与实验数据的广泛比较。
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Reference Correlation for the Viscosity of Nitrogen from the Triple Point to 1000 K and Pressures up to 2200 MPa

We present a new wide-ranging correlation for the viscosity of nitrogen based on critically evaluated experimental data as well as ab-initio calculations. The correlation is designed to be used with densities from an existing equation of state, which is valid from the triple point to 1000 K, at pressures up to 2200 MPa. The estimated uncertainty (at the 95% confidence level) for the viscosity varies depending on the temperature and pressure, from a low of 0.2% in the dilute-gas range near room temperature, to 4% for the liquid phase at pressures from saturation up to 34 MPa, and maximum of 8% in the supercritical region at pressures above 650 MPa. Extensive comparisons with experimental data are provided.

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来源期刊
CiteScore
4.10
自引率
9.10%
发文量
179
审稿时长
5 months
期刊介绍: International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.
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