不同热通量下多相 HfC-SiC 基复合材料的界面力学和烧蚀演化行为

IF 5.8 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of The European Ceramic Society Pub Date : 2024-09-30 DOI:10.1016/j.jeurceramsoc.2024.116958
Xinhao Shi , Liping Wang , Wanbo Hou , Jiahui Ding , Tao Feng , Hongjiao Lin , Mingde Tong
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引用次数: 0

摘要

采用组合工艺制备了多相 HfC-SiC 陶瓷基复合材料。研究了界面力学和烧蚀特性行为。通过引入 PyC-SiC 界面,复合材料显示出二阶拉拔机制。力学失效模型显示,纤维和基体在载荷作用下的失效应变因先失效的组分而异。此外,中心区域的烧蚀气流会通过产生的热冲击微裂缝扩散到边缘区域。随着热通量的增加,裂纹宽度逐渐增大,形成沟状。这加速了表面形貌的演变,表明 HfC-SiC 衬底在 1680 ℃ 至 2150 ℃ 的氧化产物相变过程中首先转化为 Hf-Si-O 固溶体,最终烧结为 HfO2。氧化产物形态的改变消耗了更多的热量,保护了基底免受氧化,从而提高了复合材料的抗烧蚀性。
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The interface mechanical and ablative evolution behaviors under different heat flux of multiphase HfC-SiC matrix composites
Multiphase HfC-SiC ceramic matrix composites were prepared by a combination process. The interface mechanics and ablation properties behaviors were investigated. Introducing the PyC-SiC interface, the composites showed a second-order pull-out mechanism. The mechanical failure model showed that fibers and matrix have different failure strain under load depending on the component that fails first. Moreover, the ablative airflow in the center area will spread to the edge area through the thermal shock microcracks generated. Increasing of the heat flux, the crack width gradually increased to be ditches. It accelerated the evolution of surface morphology, which showed HfC-SiC substrate was first transformed into Hf-Si-O solid solution on the process of phase transformation of oxidation products from 1680 ℃ to 2150 ℃, and eventually sintered into HfO2. The change in the morphology of oxidation product consumed more heat and protected the substrate from oxidation, resulting in improving the ablation resistance of composites.
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来源期刊
Journal of The European Ceramic Society
Journal of The European Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
10.70
自引率
12.30%
发文量
863
审稿时长
35 days
期刊介绍: The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.
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