六羰基钼在有机合成中的应用

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC Tetrahedron Pub Date : 2024-09-16 DOI:10.1016/j.tet.2024.134264

Sambasivarao Kotha , Vidyasagar Gaikwad , Usha Nandan Chaurasia

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引用次数: 0

摘要

在此，我们介绍了 Mo(CO)6 在各种有机转化中的作用，如保森-汉德反应、羰基插入、环氧化、氧化、氢化、还原、[2 + 2+2] 环加成和环化顺序。本综述概述了该试剂的用途和潜力，并介绍了一些天然产物和其他相关化合物。如果使用其他催化剂，许多反应和过程都无法进行。Mo(CO)6促进的反应也能积极改善结果。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Application of molybdenum hexacarbonyl in organic synthesis

Here, we describe the role of Mo(CO)₆ in various organic transformations such as Pauson-Khand reaction, carbonyl insertion, epoxidation, oxidation, hydrogenation, reduction, [2 + 2+2] cycloaddition, and cyclization sequences. An overview of the reagent's utility and potential is presented in this review, which presents some natural products as well as other relevant compounds. Many reactions and processes are not possible if we use other catalysts. The reactions facilitated by Mo(CO)₆ also improve the outcome positively.

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来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.