{"title":"封面专题：利用太阳能促进 Re(I)Dipyrrinato 复合物氧化有机化合物（《亚洲化学杂志》19/2024）","authors":"Shekhar Kumar, Kritika Agarwal, Sanyam, Anirban Mondal, Iti Gupta","doi":"10.1002/asia.202481902","DOIUrl":null,"url":null,"abstract":"<p>In this cover, rhenium(I)dipyrrinato complex serves as a photocatalyst in the light-assisted oxidation of organic compounds. Under light exposure, rhenium(I)dipyrrinato complex facilitates formation of singlet oxygen, which acts as oxidant for the reactions. The rhenium(I)dipyrrinato complex efficiently catalyzes two distinct types of reactions in the presence of white LED and/or sunlight. The conversion of thioether into sulfoxides and photo-oxidative benzylamine coupling reactions works well under the sunlight/white LED with 97% products yield. More details can be found in article number e202400680 by Anirban Mondal, Iti Gupta and co-workers.<figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/asia.202481902","citationCount":"0","resultStr":"{\"title\":\"Cover Feature: Harnessing Solar Power for Oxidation of Organic Compounds by Re(I)Dipyrrinato Complexes (Chem. Asian J. 19/2024)\",\"authors\":\"Shekhar Kumar, Kritika Agarwal, Sanyam, Anirban Mondal, Iti Gupta\",\"doi\":\"10.1002/asia.202481902\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this cover, rhenium(I)dipyrrinato complex serves as a photocatalyst in the light-assisted oxidation of organic compounds. Under light exposure, rhenium(I)dipyrrinato complex facilitates formation of singlet oxygen, which acts as oxidant for the reactions. The rhenium(I)dipyrrinato complex efficiently catalyzes two distinct types of reactions in the presence of white LED and/or sunlight. The conversion of thioether into sulfoxides and photo-oxidative benzylamine coupling reactions works well under the sunlight/white LED with 97% products yield. More details can be found in article number e202400680 by Anirban Mondal, Iti Gupta and co-workers.<figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":145,\"journal\":{\"name\":\"Chemistry - An Asian Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/asia.202481902\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - An Asian Journal\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/asia.202481902\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/asia.202481902","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
在本研究中，铼（I）二吡咯烷络合物在有机化合物的光辅助氧化过程中充当光催化剂。在光照射下，铼（I）二吡咯烷络合物可促进单线态氧的形成，单线态氧可作为反应的氧化剂。在白色发光二极管和/或阳光的作用下，铼（I）二吡咯烷配合物能有效催化两种不同类型的反应。在阳光/白光 LED 的作用下，硫醚转化为硫醚和光氧化苄胺偶联反应效果良好，产物收率达 97%。更多详情可参阅 Anirban Mondal、Iti Gupta 及合作者发表的编号为 e202400680 的文章。
Cover Feature: Harnessing Solar Power for Oxidation of Organic Compounds by Re(I)Dipyrrinato Complexes (Chem. Asian J. 19/2024)
In this cover, rhenium(I)dipyrrinato complex serves as a photocatalyst in the light-assisted oxidation of organic compounds. Under light exposure, rhenium(I)dipyrrinato complex facilitates formation of singlet oxygen, which acts as oxidant for the reactions. The rhenium(I)dipyrrinato complex efficiently catalyzes two distinct types of reactions in the presence of white LED and/or sunlight. The conversion of thioether into sulfoxides and photo-oxidative benzylamine coupling reactions works well under the sunlight/white LED with 97% products yield. More details can be found in article number e202400680 by Anirban Mondal, Iti Gupta and co-workers.
期刊介绍：
Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics.
Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews.
A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal.
Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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