{"title":"阳离子在La0.27Y0.73PO4-nH2O纳米颗粒中的梯度分布","authors":"M.O. Enikeeva , O.V. Proskurina , E.Yu. Gerasimov , Yu.E. Gorshkova , A.A. Naberezhnov , V.V. Gusarov","doi":"10.1016/j.physb.2024.416623","DOIUrl":null,"url":null,"abstract":"<div><div>The structure of gradient rhabdophane nanoparticles of variable composition (La,Y)PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O obtained by precipitation is considered. According to the data of HAADF TEM and EDX mapping using the Abel inversion procedure, it was shown that there is an inhomogeneous distribution of yttrium and lanthanum atoms in the particles from the central part to the periphery. At the same time, the nominal composition of both individual nanoparticles and the entire sample meets the value specified during synthesis within the error of the method – La<sub>0.27</sub>Y<sub>0.73</sub>PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O. According to SAXS data, it was determined that in the particles of (La,Y)PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O, there is a redistribution of scattering densities, which is caused by an increase in the fraction of YPO<sub>4</sub> in the peripheral region of the particles. The observed effect of the distribution of cations over the particle made it possible to determine the size of the gradient layer, which reaches 50 % of the total particle size.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":"696 ","pages":"Article 416623"},"PeriodicalIF":2.8000,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gradient distribution of cations in rhabdophane La0.27Y0.73PO4·nH2O nanoparticles\",\"authors\":\"M.O. Enikeeva , O.V. Proskurina , E.Yu. Gerasimov , Yu.E. Gorshkova , A.A. Naberezhnov , V.V. Gusarov\",\"doi\":\"10.1016/j.physb.2024.416623\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The structure of gradient rhabdophane nanoparticles of variable composition (La,Y)PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O obtained by precipitation is considered. According to the data of HAADF TEM and EDX mapping using the Abel inversion procedure, it was shown that there is an inhomogeneous distribution of yttrium and lanthanum atoms in the particles from the central part to the periphery. At the same time, the nominal composition of both individual nanoparticles and the entire sample meets the value specified during synthesis within the error of the method – La<sub>0.27</sub>Y<sub>0.73</sub>PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O. According to SAXS data, it was determined that in the particles of (La,Y)PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O, there is a redistribution of scattering densities, which is caused by an increase in the fraction of YPO<sub>4</sub> in the peripheral region of the particles. The observed effect of the distribution of cations over the particle made it possible to determine the size of the gradient layer, which reaches 50 % of the total particle size.</div></div>\",\"PeriodicalId\":20116,\"journal\":{\"name\":\"Physica B-condensed Matter\",\"volume\":\"696 \",\"pages\":\"Article 416623\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-10-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physica B-condensed Matter\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0921452624009645\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica B-condensed Matter","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921452624009645","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Gradient distribution of cations in rhabdophane La0.27Y0.73PO4·nH2O nanoparticles
The structure of gradient rhabdophane nanoparticles of variable composition (La,Y)PO4·nH2O obtained by precipitation is considered. According to the data of HAADF TEM and EDX mapping using the Abel inversion procedure, it was shown that there is an inhomogeneous distribution of yttrium and lanthanum atoms in the particles from the central part to the periphery. At the same time, the nominal composition of both individual nanoparticles and the entire sample meets the value specified during synthesis within the error of the method – La0.27Y0.73PO4·nH2O. According to SAXS data, it was determined that in the particles of (La,Y)PO4·nH2O, there is a redistribution of scattering densities, which is caused by an increase in the fraction of YPO4 in the peripheral region of the particles. The observed effect of the distribution of cations over the particle made it possible to determine the size of the gradient layer, which reaches 50 % of the total particle size.
期刊介绍：
Physica B: Condensed Matter comprises all condensed matter and material physics that involve theoretical, computational and experimental work.
Papers should contain further developments and a proper discussion on the physics of experimental or theoretical results in one of the following areas:
-Magnetism
-Materials physics
-Nanostructures and nanomaterials
-Optics and optical materials
-Quantum materials
-Semiconductors
-Strongly correlated systems
-Superconductivity
-Surfaces and interfaces
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