通过水热法一步合成二维双钌量子点纳米吸附剂,有效捕获水中的 As(V)

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY BMC Chemistry Pub Date : 2024-10-17 DOI:10.1186/s13065-024-01308-x
Saad S. M. Hassan, Mohamed E. Mahmoud, Rana M. Tharwat, Amir M. Abdelfattah
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引用次数: 0

摘要

众所周知,砷对人类具有毒性影响。因此,要从受污染的水中去除此类污染物,就必须采用高效的去除方法。本研究通过 Bi(NO3)3-5H2O 一锅水热转化反应制备了双钌量子点(Bi-ene-QDs)。Bii-ene-QDs 呈半球形结晶,大小为 6.0 nm 157.78 m2/g。因此,Bi-ene-QDs 在 pH 值为 3、相互作用持续时间为 40 分钟、Bi-ene-QDs 用量为 10 毫克的条件下捕获 As(V)的效果最佳。As(V) 离子与 Bi-ene-QDs 的相互作用通过出现 As-O 伸展振动得到了证实。此外,Bi-ene-QDs 对海水、自来水和废水中的砷离子具有极佳的吸附捕获率,在 5 mg L-1 的砷离子污染样品中分别达到 94.61%、95.21% 和 94.38%。因此,Bi-ene-QDs 是一种前所未有的高效纳米吸附剂,可成功去除各种废水基质中的砷离子污染,效率高达 90.0%。
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Effective capture of As(V) from water by a facile one step hydrothermal synthesized of 2-D bismuthene quantum dots nanosorbent

Arsenic species have been known for their toxic impact on human. Therefore, removal of such pollutant requires efficient and effective removal methodology from polluted water. In this study, bismuthene quantum dots (Bi-ene-QDs) were fabricated by a green and facile one pot-hydrothermal conversion reaction of Bi(NO3)3·5H2O. Bi-ene-QDs exhibited semi-spherical crystalline providing 6.0 nm 157.78 m2/g. Consequently, As(V) capturing by Bi-ene-QDs revealed optimum practical conditions at pH 3, interaction duration time 40 min and 10 mg Bi-ene-QDs dosage. The interaction of As(V) ions with Bi-ene-QDs were confirmed by the appearance of As-O stretching vibration. Moreover, Bi-ene-QDs achieved excellent adsorptive capture percentages of Arsenic ions from sea, tap and wastewater providing 94.61, 95.21 and 94.38% from contaminated samples with 5 mg L−1 Arsenic ions. Therefore, Bi-ene-QDs can be categorized as an unprecedented and efficient nanosorbent for the successful removal of Arsenic ions pollution from various wastewater matrices with > 90.0% efficiency.

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来源期刊
BMC Chemistry
BMC Chemistry Chemistry-General Chemistry
CiteScore
5.30
自引率
2.20%
发文量
92
审稿时长
27 weeks
期刊介绍: BMC Chemistry, formerly known as Chemistry Central Journal, is now part of the BMC series journals family. Chemistry Central Journal has served the chemistry community as a trusted open access resource for more than 10 years – and we are delighted to announce the next step on its journey. In January 2019 the journal has been renamed BMC Chemistry and now strengthens the BMC series footprint in the physical sciences by publishing quality articles and by pushing the boundaries of open chemistry.
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