{"title":"用于灵敏柔性传感器的具有大双轴应变和共形粘附性的超软导电聚合物水凝胶","authors":"Xiaojiao Shi, Linli Xu, Qiuli Xu, Na Li, Xinyu Li, Yubin Zhang, Zhihui Qin, Tifeng Jiao","doi":"10.1021/acs.chemmater.4c01909","DOIUrl":null,"url":null,"abstract":"Conducting polymer hydrogels have been considered as promising materials for flexible sensors. The integrated performances of ultrasoftness, high deformation, mechanical robustness, conformal adhesion, and high sensitivity are of great importance for their applications in wearable sensors but still remains challenging. Herein, a highly deformable conducting polymer hydrogel with ultrasoftness, tear resistance, and self-adhesiveness is fabricated by incorporating poly(3, 4-ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS) and silk sericin (SS) into a covalently cross-linked polyacrylamide (PAM) network. Owing to abundant noncovalent interactions among the folded SS chains, PAM chains, and PEDOT:PSS, the obtained hydrogel shows a low modulus (10.3 kPa), ultrastretchability (>2000%), particularly large biaxial strain (an areal strain of 1700%), high toughness (tearing energy of 2.5 kJ/m<sup>2</sup>), and good conformal adhesion. As a result, this hydrogel demonstrates superior strain-sensitivity (gauge factor = 13.8) in a broad strain range (2000%) and excellent sensing reproducibility. The hydrogel-based wearable sensor can be used for accurately monitoring large and tiny human movements in real time and serves as bioelectrodes for precise gathering of electrocardiography and electromyography signals, showing great potential for applications in flexible sensing devices.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":7.2000,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ultrasoft Conducting Polymer Hydrogels with Large Biaxial Strain and Conformal Adhesion for Sensitive Flexible Sensors\",\"authors\":\"Xiaojiao Shi, Linli Xu, Qiuli Xu, Na Li, Xinyu Li, Yubin Zhang, Zhihui Qin, Tifeng Jiao\",\"doi\":\"10.1021/acs.chemmater.4c01909\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Conducting polymer hydrogels have been considered as promising materials for flexible sensors. The integrated performances of ultrasoftness, high deformation, mechanical robustness, conformal adhesion, and high sensitivity are of great importance for their applications in wearable sensors but still remains challenging. Herein, a highly deformable conducting polymer hydrogel with ultrasoftness, tear resistance, and self-adhesiveness is fabricated by incorporating poly(3, 4-ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS) and silk sericin (SS) into a covalently cross-linked polyacrylamide (PAM) network. Owing to abundant noncovalent interactions among the folded SS chains, PAM chains, and PEDOT:PSS, the obtained hydrogel shows a low modulus (10.3 kPa), ultrastretchability (>2000%), particularly large biaxial strain (an areal strain of 1700%), high toughness (tearing energy of 2.5 kJ/m<sup>2</sup>), and good conformal adhesion. As a result, this hydrogel demonstrates superior strain-sensitivity (gauge factor = 13.8) in a broad strain range (2000%) and excellent sensing reproducibility. The hydrogel-based wearable sensor can be used for accurately monitoring large and tiny human movements in real time and serves as bioelectrodes for precise gathering of electrocardiography and electromyography signals, showing great potential for applications in flexible sensing devices.\",\"PeriodicalId\":33,\"journal\":{\"name\":\"Chemistry of Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":7.2000,\"publicationDate\":\"2024-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry of Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.chemmater.4c01909\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acs.chemmater.4c01909","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Ultrasoft Conducting Polymer Hydrogels with Large Biaxial Strain and Conformal Adhesion for Sensitive Flexible Sensors
Conducting polymer hydrogels have been considered as promising materials for flexible sensors. The integrated performances of ultrasoftness, high deformation, mechanical robustness, conformal adhesion, and high sensitivity are of great importance for their applications in wearable sensors but still remains challenging. Herein, a highly deformable conducting polymer hydrogel with ultrasoftness, tear resistance, and self-adhesiveness is fabricated by incorporating poly(3, 4-ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS) and silk sericin (SS) into a covalently cross-linked polyacrylamide (PAM) network. Owing to abundant noncovalent interactions among the folded SS chains, PAM chains, and PEDOT:PSS, the obtained hydrogel shows a low modulus (10.3 kPa), ultrastretchability (>2000%), particularly large biaxial strain (an areal strain of 1700%), high toughness (tearing energy of 2.5 kJ/m2), and good conformal adhesion. As a result, this hydrogel demonstrates superior strain-sensitivity (gauge factor = 13.8) in a broad strain range (2000%) and excellent sensing reproducibility. The hydrogel-based wearable sensor can be used for accurately monitoring large and tiny human movements in real time and serves as bioelectrodes for precise gathering of electrocardiography and electromyography signals, showing great potential for applications in flexible sensing devices.
期刊介绍:
The journal Chemistry of Materials focuses on publishing original research at the intersection of materials science and chemistry. The studies published in the journal involve chemistry as a prominent component and explore topics such as the design, synthesis, characterization, processing, understanding, and application of functional or potentially functional materials. The journal covers various areas of interest, including inorganic and organic solid-state chemistry, nanomaterials, biomaterials, thin films and polymers, and composite/hybrid materials. The journal particularly seeks papers that highlight the creation or development of innovative materials with novel optical, electrical, magnetic, catalytic, or mechanical properties. It is essential that manuscripts on these topics have a primary focus on the chemistry of materials and represent a significant advancement compared to prior research. Before external reviews are sought, submitted manuscripts undergo a review process by a minimum of two editors to ensure their appropriateness for the journal and the presence of sufficient evidence of a significant advance that will be of broad interest to the materials chemistry community.