共价有机框架的光催化应用：合成、表征和实用性

IF 5.8 3区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Nanoscale Pub Date : 2024-10-21 DOI:10.1039/d4nr03204g

Jared G Doremus, Bertha Lotsi, Aadarsh Sharma, Psaras L McGrier

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引用次数: 0

摘要

光催化已成为一种高效安全的有机转化方法，许多半导体已被研究用作光催化剂。共价有机框架（COFs）是一类成熟的结晶多孔材料，由易于调整的有机单元构成。COFs 具有重要的半导体特性和可观的光电行为，使其成为一种前景广阔的光催化剂。在本综述中，我们总结了 COFs 的设计、合成方法和炭化技术。此外，还讨论了提高光催化性能的策略。然后详细介绍了 COFs 作为光催化剂在各种反应中的应用。最后，总结了将 COFs 发展为高效光催化剂所面临的挑战和未来机遇。

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Photocatalytic Applications of Covalent Organic Frameworks: Synthesis, Characterization, and Utility

Photocatalysis has emerged as an energy efficient and safe method to perform organic transformations, and many semiconductors have been studied for use as photocatalysts. Covalent organic frameworks (COFs) are an established class of crystalline, porous materials constucted from organic units that are easily tunable. COFs importantly display semiconductor properties and respectable photoelectric behavior making them a strong prospect as photocatalysts. In this review, we summarzie the design, synthesis methods, and charazization techniques for COFs. Strategies to boost photocatalytic performance is also discussed. Then the application of COFs as photocatalysts in a variety of reactions is detailed. Finally, a summary, challenges, and future opportunities for the development of COFs as efficient photocatalysts are entailed.

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来源期刊

Nanoscale CHEMISTRY, MULTIDISCIPLINARY-NANOSCIENCE & NANOTECHNOLOGY

CiteScore

12.10

自引率

3.00%

发文量

1628

审稿时长

1.6 months

期刊介绍： Nanoscale is a high-impact international journal, publishing high-quality research across nanoscience and nanotechnology. Nanoscale publishes a full mix of research articles on experimental and theoretical work, including reviews, communications, and full papers.Highly interdisciplinary, this journal appeals to scientists, researchers and professionals interested in nanoscience and nanotechnology, quantum materials and quantum technology, including the areas of physics, chemistry, biology, medicine, materials, energy/environment, information technology, detection science, healthcare and drug discovery, and electronics.