IF 2.9 3区 化学 Q3 CHEMISTRY, PHYSICAL Soft Matter Pub Date : 2024-10-22 DOI:10.1039/d4sm00350k
Subhajit Paul, Abhishek Dhar, Debasish Chaudhuri
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引用次数: 0

摘要

我们探讨了主动粒子谐波链中示踪剂的动力学,研究了相互作用的影响。我们的分析包括通过格林函数技术和数值模拟计算均方位移(MSD)和时空相关性。根据链的特性,即由相互作用刚度和活动持续性决定的不同时间尺度,标记粒子的 MSD 随时间呈现弹道、扩散和单排扩散(SFD)缩放,我们的分析表达式解释了交叉。我们的研究结果揭示了大量粒子位移分布从早期的双峰分布到晚期的高斯分布的转变,经历了具有有限支持和负过高峰度的单峰分布和具有正过高峰度的长尾分布。在适当的时间范围内,这些分布表现出数据塌缩,与弹道、扩散和 SFD 缩放一致。然而,在更长的时间内,分布变成了高斯分布。最后,我们推导出稳态静态和动态两点位移相关性的解析表达式。我们通过模拟验证了这些表达式,并强调了与平衡结果的差异。
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Dynamical crossovers and correlations in a harmonic chain of active particles.

We explore the dynamics of a tracer in an active particle harmonic chain, investigating the influence of interactions. Our analysis involves calculating mean-squared displacements (MSDs) and space-time correlations through Green's function techniques and numerical simulations. Depending on chain characteristics, i.e., different time scales determined by interaction stiffness and persistence of activity, tagged-particle MSDs exhibit ballistic, diffusive, and single-file diffusion (SFD) scaling over time, with crossovers explained by our analytic expressions. Our results reveal transitions in bulk particle displacement distributions from an early-time bimodal to late-time Gaussian, passing through regimes of unimodal distributions with finite support and negative excess kurtosis and longer-tailed distributions with positive excess kurtosis. The distributions exhibit data collapse, aligning with ballistic, diffusive, and SFD scaling in the appropriate time regimes. However, at much longer times, the distributions become Gaussian. Finally, we derive analytic expressions for steady-state static and dynamic two-point displacement correlations. We verify these from simulations and highlight the differences from the equilibrium results.

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来源期刊
Soft Matter
Soft Matter 工程技术-材料科学:综合
CiteScore
6.00
自引率
5.90%
发文量
891
审稿时长
1.9 months
期刊介绍: Where physics meets chemistry meets biology for fundamental soft matter research.
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