Anodized SLM Ti6Al4V surfaces: influence of surface characteristics on NTs growth and resulted surfaces properties†

TiO₂ nanotubes (NTs) obtained via electrochemical anodization (EA) on conventionally machined titanium surfaces are reported to be promising for achieving mucointegration in dental implant therapy. Dental abutments, manufactured by selective laser melting (SLM), combined with thermal post-treatment, present a promising alternative to conventionally machined titanium. Based on an original protocol, this study aims to investigate how the characteristic microstructure of the α + β phases in post-heated SLM Ti6Al4V can influence the growth of NTs and the resulting physical and chemical surface properties. Ti6Al4V-SLM discs were fabricated, heat post-treated and mechanically polished. The samples were then subjected to EA under different voltage conditions (10, 20 and 30 V). The specimens’ surfaces were characterized at the same location, before NTs formation by electron backscatter diffraction (EBSD), and after by scanning electron microscopy (SEM). Then, roughness and wettability were studied to determine how EA affects surface properties compared to conventionally machined and polished titanium surfaces without NTs (reference). Surface reactivity was evaluated through chemical analysis and collagen binding capacities. The self-organized TiO₂ layer was developed on the α phase only and the β phase was preferentially dissolved. The characteristic dimensions of the nanotubes (diameter, length and wall thickness), measured by SEM image analysis, increased proportionally with the rise in voltage but were not affected by the crystallographic orientation of the underlying α grain. Micro-roughness was the same for nanotubular and reference surfaces. Wettability was improved, as was surface reactivity towards collagen, which may contribute to improved bioactivity of titanium surfaces in dentistry.