A review of ordered PtCo3 catalyst with higher oxygen reduction reaction activity in proton exchange membrane fuel cells

This review is devoted to the potential advantages of ordered alloy catalysts in proton exchange membrane fuel cells (PEMFCs), specifically focusing on the development of the low Pt content, high activity, and durability ordered PtCo₃ catalyst. Due to the sluggish oxygen reduction reaction (ORR) kinetics and poor durability, the overall performance of the fuel cell is affected, and its application and promotion are limited. To address this issue, researchers have explored various synthetic strategies, such as element doping, morphology adjusting, structure controlling, ordering and support/metal interaction enhancement. This article extensively discussed the Pt related ORR catalysts and follows an in-depth analysis of ordered PtCo₃. The introduction briefly discusses the direction of development of fuel cell catalysts and frontier progress, including theoretical mechanism, practical preparation, and Pt-containing electrode structures, etc. The subsequent chapter focuses on the Pt-Co catalyst, the evolution process of Pt alloy to Pt-Co alloy and the improvement scheme are introduced. The next chapter describes the properties of PtCo₃. Although the ordered PtCo₃ catalyst has a wide range of applicability due to low cost and high activity catalyst. However, besides the common agglomeration and sintering problems of Pt-Co alloy, its commercial application still faces unique problems of oversized crystal size, phase segregation, ordering transformation and transition metal dissolution. Therefore, in Chapter 4, this overview provides some possible improvement methods for three specific functions: crystal refinement, enhancing the effect of support and active substances, and anti-dissolution.