D. A. Movenko, A. V. Zavodov, A. B. Laptev, A. O. Loschinina
{"title":"单晶镍基超级合金在 750°C 高温盐腐蚀过程中的结构变化","authors":"D. A. Movenko, A. V. Zavodov, A. B. Laptev, A. O. Loschinina","doi":"10.1007/s11041-024-01047-9","DOIUrl":null,"url":null,"abstract":"<p>The VZhM4 single-crystal Ni-based superalloy was tested for high-temperature salt-induced corrosion resistance in Na<sub>2</sub>SO<sub>4</sub> + NaCl at 750°C. The equilibrium composition of phases formed during the interaction of the alloy with oxygen and sulfur across the temperature range of 600 – 1000°C were calculated. Changes in the structure and composition of the surface layer of the alloy during high-temperature salt corrosion were studied using scanning and transmission electron microscopy. The results obtained were used to compile structural diagrams for the corrosion layer formed on the alloy after 5 and 20 test cycles. The quantitative composition of the main phases in the corrosion products was determined. A qualitative assessment of Re, Ta, and Ru diffusion was performed.</p>","PeriodicalId":701,"journal":{"name":"Metal Science and Heat Treatment","volume":"66 5-6","pages":"277 - 285"},"PeriodicalIF":0.6000,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Changing the Structure of a Single-Crystal Ni-Based Superalloy During Its High-Temperature Salt Corrosion at 750°C\",\"authors\":\"D. A. Movenko, A. V. Zavodov, A. B. Laptev, A. O. Loschinina\",\"doi\":\"10.1007/s11041-024-01047-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The VZhM4 single-crystal Ni-based superalloy was tested for high-temperature salt-induced corrosion resistance in Na<sub>2</sub>SO<sub>4</sub> + NaCl at 750°C. The equilibrium composition of phases formed during the interaction of the alloy with oxygen and sulfur across the temperature range of 600 – 1000°C were calculated. Changes in the structure and composition of the surface layer of the alloy during high-temperature salt corrosion were studied using scanning and transmission electron microscopy. The results obtained were used to compile structural diagrams for the corrosion layer formed on the alloy after 5 and 20 test cycles. The quantitative composition of the main phases in the corrosion products was determined. A qualitative assessment of Re, Ta, and Ru diffusion was performed.</p>\",\"PeriodicalId\":701,\"journal\":{\"name\":\"Metal Science and Heat Treatment\",\"volume\":\"66 5-6\",\"pages\":\"277 - 285\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-10-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Metal Science and Heat Treatment\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11041-024-01047-9\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Metal Science and Heat Treatment","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11041-024-01047-9","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Changing the Structure of a Single-Crystal Ni-Based Superalloy During Its High-Temperature Salt Corrosion at 750°C
The VZhM4 single-crystal Ni-based superalloy was tested for high-temperature salt-induced corrosion resistance in Na2SO4 + NaCl at 750°C. The equilibrium composition of phases formed during the interaction of the alloy with oxygen and sulfur across the temperature range of 600 – 1000°C were calculated. Changes in the structure and composition of the surface layer of the alloy during high-temperature salt corrosion were studied using scanning and transmission electron microscopy. The results obtained were used to compile structural diagrams for the corrosion layer formed on the alloy after 5 and 20 test cycles. The quantitative composition of the main phases in the corrosion products was determined. A qualitative assessment of Re, Ta, and Ru diffusion was performed.
期刊介绍:
Metal Science and Heat Treatment presents new fundamental and practical research in physical metallurgy, heat treatment equipment, and surface engineering.
Topics covered include:
New structural, high temperature, tool and precision steels;
Cold-resistant, corrosion-resistant and radiation-resistant steels;
Steels with rapid decline of induced properties;
Alloys with shape memory effect;
Bulk-amorphyzable metal alloys;
Microcrystalline alloys;
Nano materials and foam materials for medical use.