聚苯乙烯基闪烁体的抛光机理

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Superhard Materials Pub Date : 2024-10-27 DOI:10.3103/S1063457624050034
Yu. D. Filatov, A. Y. Boyarintsev, V. I. Sidorko, S. V. Kovalev, O. V. Kolesnikov, V. O. Novgorodtsev, Ya. I. Polupan
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引用次数: 0

摘要

摘要--通过研究聚苯乙烯闪烁体使用微粉和纳米粉分散系统进行抛光的机理,确定了污泥纳米颗粒(SP)和抛光粉磨损颗粒(PP)的形成是由于在由处理过的材料和抛光粉颗粒表面形成的开放式微共振器中发生了四种模式下的佛斯特共振能量转移(FRET)。实验证明,抛光分散系统中的分散相颗粒的磨损速度比处理材料的去除速度快两倍。在由处理过的材料和搭接面形成的开放式谐振器中,量子纳米粒子在 PP 上散射时 SP 的总横截面(31.1 Mb)远大于 PP 在 SP 上散射时的总横截面,从而导致在处理过的表面上没有抛光粉磨损纳米粒子的沉积物,而在搭接面上有污泥纳米粒子的沉积物。材料去除率的计算结果与聚苯乙烯抛光率的实验测量数据一致,偏差不超过 4%,搭接表面上的 SP 沉积物碎片大小为 0.2 至 1.0 毫米,在半径为 24.5 毫米的环形区域内离散排列。用微颗粒和纳米颗粒分散系统抛光聚苯乙烯闪烁元件的结果表明,高纵横比探测器对快中子和伽马量子脉冲形状的辨别能力提高了 14%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Mechanism of Polishing for Polystyrene Based Scintillators

Abstract—As a result of studying the mechanism of polishing with a disperse system from micro- and nanopowders for polystyrene scintillators, sludge nanoparticles (SP) and polishing powder wear particles (PP) were established to form due to Förster resonance energy transfer (FRET) occurring in a four-mode regime in the open microresonator formed by the surfaces of a treated material and a polishing powder particle. The disperse phase particles in the polishing disperse system were demonstrated to wear twice faster as compared to treated material removal. The total cross section of SPs scattering on PPs (31.1 Mb) during the scattering of quantum nanoparticles in the open resonator formed by the treated material and lap surfaces was shown to be much larger than the total cross section of PPs scattering on SPs to result in the absence of a deposit from polishing powder wear nanoparticles on the treated surface and the presence of a deposit from sludge nanoparticles on the lap surface. The results of calculating the material removal rate were established to agree with the data of experimental polystyrene polishing rate measurements at a deviation up to 4%, and SP deposit fragments on the lap surface were from 0.2 to 1.0 mm in size and discretely arranged within an annular zone with a radius of 24.5 mm. The polishing of polystyrene based scintillation elements with a disperse system from micro- and nanoparticles was shown to improve the pulse shape discrimination of fast neutrons and gamma quanta by high aspect ratio detectors by 14%.

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来源期刊
Journal of Superhard Materials
Journal of Superhard Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
1.80
自引率
66.70%
发文量
26
审稿时长
2 months
期刊介绍: Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.
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