钛酸钆 Gd2Ti2O7 的热力学性质

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2024-10-28 DOI:10.1134/S0036024424701620

P. G. Gagarin, A. V. Guskov, V. N. Guskov, A. V. Khoroshilov, K. S. Gavrichev

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引用次数: 0

摘要

在 2-1825 K 的温度范围内测量了热长石钆钛酸盐 Gd2Ti2O7 的等压热容。热力学函数（熵、焓变、还原吉布斯能）是利用热容量的一致平滑值计算得出的。估计了高温范围内由氧化物形成 Gd2Ti2O7 的吉布斯能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Thermodynamic Properties of Gadolinium Titanate Gd2Ti2O7

The isobaric heat capacity of pyrochlore gadolinium titanate Gd₂Ti₂O₇ is measured in the 2–1825 K range of temperatures. Thermodynamic functions (entropy, enthalpy change, reduced Gibbs energy) are calculated using consistent smoothed values of heat capacity. The Gibbs energy of the formation of Gd₂Ti₂O₇ from oxides in the high temperature range is estimated.

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.