{"title":"银（I）离子在非水溶剂中的溶解热力学","authors":"I. A. Kuz’mina, M. A. Kovanova","doi":"10.1134/S0036024424701644","DOIUrl":null,"url":null,"abstract":"<p>The Gibbs energies of the transfer of the silver(I) ion from methanol (MeOH) to dimethyl sulfoxide (DMSO) and from ethanol (EtOH) to <i>N</i>,<i>N</i>-dimethylformamide (DMF) were determined by potentio-metry. Our own and literature data on the thermodynamic characteristics of the transfer of Ag<sup>+</sup> from alcohols (S<sub>1</sub>) to aprotic (S<sub>2</sub>) solvents were summarized and analyzed. It has been established that the replacement of amphoteric solvents with aprotic ones leads to significantly increased solvation of the silver(I) ion. The enthalpy contribution to the Gibbs energy of ion transfer in the case of the replacement (S<sub>1</sub> → S<sub>2</sub>) is dominant. The strengthening of solvate complexes of Ag<sup>+</sup> with solvent in the case of the replacement of S<sub>1</sub> by S<sub>2</sub> is caused mainly by an increase in the electron donor-acceptor (EDA) interactions due to a decrease in the acidity of solvents.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermodynamics of Solvation of Silver(I) Ion in Nonaqueous Solvents\",\"authors\":\"I. A. Kuz’mina, M. A. Kovanova\",\"doi\":\"10.1134/S0036024424701644\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The Gibbs energies of the transfer of the silver(I) ion from methanol (MeOH) to dimethyl sulfoxide (DMSO) and from ethanol (EtOH) to <i>N</i>,<i>N</i>-dimethylformamide (DMF) were determined by potentio-metry. Our own and literature data on the thermodynamic characteristics of the transfer of Ag<sup>+</sup> from alcohols (S<sub>1</sub>) to aprotic (S<sub>2</sub>) solvents were summarized and analyzed. It has been established that the replacement of amphoteric solvents with aprotic ones leads to significantly increased solvation of the silver(I) ion. The enthalpy contribution to the Gibbs energy of ion transfer in the case of the replacement (S<sub>1</sub> → S<sub>2</sub>) is dominant. The strengthening of solvate complexes of Ag<sup>+</sup> with solvent in the case of the replacement of S<sub>1</sub> by S<sub>2</sub> is caused mainly by an increase in the electron donor-acceptor (EDA) interactions due to a decrease in the acidity of solvents.</p>\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-10-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024424701644\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424701644","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Thermodynamics of Solvation of Silver(I) Ion in Nonaqueous Solvents
The Gibbs energies of the transfer of the silver(I) ion from methanol (MeOH) to dimethyl sulfoxide (DMSO) and from ethanol (EtOH) to N,N-dimethylformamide (DMF) were determined by potentio-metry. Our own and literature data on the thermodynamic characteristics of the transfer of Ag+ from alcohols (S1) to aprotic (S2) solvents were summarized and analyzed. It has been established that the replacement of amphoteric solvents with aprotic ones leads to significantly increased solvation of the silver(I) ion. The enthalpy contribution to the Gibbs energy of ion transfer in the case of the replacement (S1 → S2) is dominant. The strengthening of solvate complexes of Ag+ with solvent in the case of the replacement of S1 by S2 is caused mainly by an increase in the electron donor-acceptor (EDA) interactions due to a decrease in the acidity of solvents.
期刊介绍：
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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