Junyoung Kim , Imtiaz Afzal Khan , Jae Won Lee , Youngnoh Kim , Seokhwan Jeon , Soryong Chae , Jong-Oh Kim
{"title":"在紫外线照射下使用臭氧同时降解医院废水中的药物和个人护理产品","authors":"Junyoung Kim , Imtiaz Afzal Khan , Jae Won Lee , Youngnoh Kim , Seokhwan Jeon , Soryong Chae , Jong-Oh Kim","doi":"10.1016/j.jwpe.2024.106366","DOIUrl":null,"url":null,"abstract":"<div><div>The discharge of Pharmaceuticals and personal care products (PPCPs) from industries and hospitals are responsible for the contamination of water body with slow or non-degradable toxic compounds. The removal of these contaminants required advanced treatment process because of unable to treat by conventional wastewater treatment process. In this study, the degradation of PPCP compounds, including caffeine (CAF), atenolol (ATL), carbamazepine (CBZ), sulfamethoxazole (SMX), trimethoprim (TMP), and acetaminophen (ACT) was evaluated under exposure to 1.0 and 1.5 mg/L dissolved ozone (O<sub>3</sub>), both with and without ultraviolet (UV) irradiation (254 nm). Using liquid chromatography with tandem mass spectrometry, we determined that the removal efficiency for the targeted contaminants exceeded 95 % within just 20 min of exposure to both 1.0 and 1.5 mg/L O<sub>3</sub>. However, when treated with UV light alone, the removal efficiency was limited at 3 %–11 %. A combination treatment involving dissolved 1.5 mg/L O<sub>3</sub> and UV light led to over 97 % removal within 7 min. This outcome was attributed to hydroxylation reactions, aromatic ring opening, oxidation, and mineralization facilitated by the HO<img> and peroxide generated through the photolysis of O<sub>3</sub>. The degradation rate of PPCP compounds followed pseudo-first-order kinetics and showed a decrease in the presence of humic acid and hospital wastewater further decreased it. Moreover, O<sub>3</sub>/UV treatment generated lower-weight degradation products. The toxicity analysis revealed that these transformation products exhibited environmental benignity and minimal health risks which O<sub>3</sub>/UV treatment potentially minimizes the presence of harmful byproducts. These findings provide a foundation for developing combined hybrid systems for PPCP containing wastewater, containing membrane filtration with ozonation system.</div></div>","PeriodicalId":17528,"journal":{"name":"Journal of water process engineering","volume":"68 ","pages":"Article 106366"},"PeriodicalIF":6.3000,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Simultaneous degradation of pharmaceuticals and personal care products in hospital wastewater using ozone under ultraviolet irradiation\",\"authors\":\"Junyoung Kim , Imtiaz Afzal Khan , Jae Won Lee , Youngnoh Kim , Seokhwan Jeon , Soryong Chae , Jong-Oh Kim\",\"doi\":\"10.1016/j.jwpe.2024.106366\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The discharge of Pharmaceuticals and personal care products (PPCPs) from industries and hospitals are responsible for the contamination of water body with slow or non-degradable toxic compounds. The removal of these contaminants required advanced treatment process because of unable to treat by conventional wastewater treatment process. In this study, the degradation of PPCP compounds, including caffeine (CAF), atenolol (ATL), carbamazepine (CBZ), sulfamethoxazole (SMX), trimethoprim (TMP), and acetaminophen (ACT) was evaluated under exposure to 1.0 and 1.5 mg/L dissolved ozone (O<sub>3</sub>), both with and without ultraviolet (UV) irradiation (254 nm). Using liquid chromatography with tandem mass spectrometry, we determined that the removal efficiency for the targeted contaminants exceeded 95 % within just 20 min of exposure to both 1.0 and 1.5 mg/L O<sub>3</sub>. However, when treated with UV light alone, the removal efficiency was limited at 3 %–11 %. A combination treatment involving dissolved 1.5 mg/L O<sub>3</sub> and UV light led to over 97 % removal within 7 min. This outcome was attributed to hydroxylation reactions, aromatic ring opening, oxidation, and mineralization facilitated by the HO<img> and peroxide generated through the photolysis of O<sub>3</sub>. The degradation rate of PPCP compounds followed pseudo-first-order kinetics and showed a decrease in the presence of humic acid and hospital wastewater further decreased it. Moreover, O<sub>3</sub>/UV treatment generated lower-weight degradation products. The toxicity analysis revealed that these transformation products exhibited environmental benignity and minimal health risks which O<sub>3</sub>/UV treatment potentially minimizes the presence of harmful byproducts. These findings provide a foundation for developing combined hybrid systems for PPCP containing wastewater, containing membrane filtration with ozonation system.</div></div>\",\"PeriodicalId\":17528,\"journal\":{\"name\":\"Journal of water process engineering\",\"volume\":\"68 \",\"pages\":\"Article 106366\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2024-10-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of water process engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2214714424015988\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of water process engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214714424015988","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Simultaneous degradation of pharmaceuticals and personal care products in hospital wastewater using ozone under ultraviolet irradiation
The discharge of Pharmaceuticals and personal care products (PPCPs) from industries and hospitals are responsible for the contamination of water body with slow or non-degradable toxic compounds. The removal of these contaminants required advanced treatment process because of unable to treat by conventional wastewater treatment process. In this study, the degradation of PPCP compounds, including caffeine (CAF), atenolol (ATL), carbamazepine (CBZ), sulfamethoxazole (SMX), trimethoprim (TMP), and acetaminophen (ACT) was evaluated under exposure to 1.0 and 1.5 mg/L dissolved ozone (O3), both with and without ultraviolet (UV) irradiation (254 nm). Using liquid chromatography with tandem mass spectrometry, we determined that the removal efficiency for the targeted contaminants exceeded 95 % within just 20 min of exposure to both 1.0 and 1.5 mg/L O3. However, when treated with UV light alone, the removal efficiency was limited at 3 %–11 %. A combination treatment involving dissolved 1.5 mg/L O3 and UV light led to over 97 % removal within 7 min. This outcome was attributed to hydroxylation reactions, aromatic ring opening, oxidation, and mineralization facilitated by the HO and peroxide generated through the photolysis of O3. The degradation rate of PPCP compounds followed pseudo-first-order kinetics and showed a decrease in the presence of humic acid and hospital wastewater further decreased it. Moreover, O3/UV treatment generated lower-weight degradation products. The toxicity analysis revealed that these transformation products exhibited environmental benignity and minimal health risks which O3/UV treatment potentially minimizes the presence of harmful byproducts. These findings provide a foundation for developing combined hybrid systems for PPCP containing wastewater, containing membrane filtration with ozonation system.
期刊介绍：
The Journal of Water Process Engineering aims to publish refereed, high-quality research papers with significant novelty and impact in all areas of the engineering of water and wastewater processing . Papers on advanced and novel treatment processes and technologies are particularly welcome. The Journal considers papers in areas such as nanotechnology and biotechnology applications in water, novel oxidation and separation processes, membrane processes (except those for desalination) , catalytic processes for the removal of water contaminants, sustainable processes, water reuse and recycling, water use and wastewater minimization, integrated/hybrid technology, process modeling of water treatment and novel treatment processes. Submissions on the subject of adsorbents, including standard measurements of adsorption kinetics and equilibrium will only be considered if there is a genuine case for novelty and contribution, for example highly novel, sustainable adsorbents and their use: papers on activated carbon-type materials derived from natural matter, or surfactant-modified clays and related minerals, would not fulfil this criterion. The Journal particularly welcomes contributions involving environmentally, economically and socially sustainable technology for water treatment, including those which are energy-efficient, with minimal or no chemical consumption, and capable of water recycling and reuse that minimizes the direct disposal of wastewater to the aquatic environment. Papers that describe novel ideas for solving issues related to water quality and availability are also welcome, as are those that show the transfer of techniques from other disciplines. The Journal will consider papers dealing with processes for various water matrices including drinking water (except desalination), domestic, urban and industrial wastewaters, in addition to their residues. It is expected that the journal will be of particular relevance to chemical and process engineers working in the field. The Journal welcomes Full Text papers, Short Communications, State-of-the-Art Reviews and Letters to Editors and Case Studies
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