{"title":"双通道氧化还原反应，用于光催化 H2 进化和废料的光转化氧化","authors":"","doi":"10.1016/S1872-2067(24)60118-X","DOIUrl":null,"url":null,"abstract":"<div><div>Dual-channel redox reaction system is advantageous for photocatalytic hydrogen (H<sub>2</sub>) production when coupled with photoreforming oxidation of waste materials, benefiting both thermodynamically and kinetically. However, existing reviews primarily focus on specific oxidation reactions, such as oxidative organic synthesis and water remediation, often neglecting recent advancements in plastic upgrading, biomass conversion, and H<sub>2</sub>O<sub>2</sub> production, and failing to provide an in-depth discussion of catalytic mechanisms. This review addresses these gaps by offering a comprehensive overview of recent advancements in dual-channel redox reactions for photocatalytic H<sub>2</sub>-evolution and waste photoreforming. It highlights waste-to-wealth design concepts, examines the challenges, advantages and diverse applications of dual-channel photocatalytic reactions, including photoreforming of biomass, alcohol, amine, plastic waste, organic pollutants, and H<sub>2</sub>O<sub>2</sub> production. Emphasizing improvement strategies and exploration of catalytic mechanisms, it includes advanced <em>in-situ</em> characterization, spin capture experiments, and DFT calculations. By identifying challenges and future directions in this field, this review provides valuable insights for designing innovative dual-channel photocatalytic systems.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":null,"pages":null},"PeriodicalIF":15.7000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dual-channel redox reactions for photocatalytic H2-evolution coupled with photoreforming oxidation of waste materials\",\"authors\":\"\",\"doi\":\"10.1016/S1872-2067(24)60118-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Dual-channel redox reaction system is advantageous for photocatalytic hydrogen (H<sub>2</sub>) production when coupled with photoreforming oxidation of waste materials, benefiting both thermodynamically and kinetically. However, existing reviews primarily focus on specific oxidation reactions, such as oxidative organic synthesis and water remediation, often neglecting recent advancements in plastic upgrading, biomass conversion, and H<sub>2</sub>O<sub>2</sub> production, and failing to provide an in-depth discussion of catalytic mechanisms. This review addresses these gaps by offering a comprehensive overview of recent advancements in dual-channel redox reactions for photocatalytic H<sub>2</sub>-evolution and waste photoreforming. It highlights waste-to-wealth design concepts, examines the challenges, advantages and diverse applications of dual-channel photocatalytic reactions, including photoreforming of biomass, alcohol, amine, plastic waste, organic pollutants, and H<sub>2</sub>O<sub>2</sub> production. Emphasizing improvement strategies and exploration of catalytic mechanisms, it includes advanced <em>in-situ</em> characterization, spin capture experiments, and DFT calculations. By identifying challenges and future directions in this field, this review provides valuable insights for designing innovative dual-channel photocatalytic systems.</div></div>\",\"PeriodicalId\":9832,\"journal\":{\"name\":\"Chinese Journal of Catalysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":15.7000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chinese Journal of Catalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S187220672460118X\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Catalysis","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S187220672460118X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Dual-channel redox reactions for photocatalytic H2-evolution coupled with photoreforming oxidation of waste materials
Dual-channel redox reaction system is advantageous for photocatalytic hydrogen (H2) production when coupled with photoreforming oxidation of waste materials, benefiting both thermodynamically and kinetically. However, existing reviews primarily focus on specific oxidation reactions, such as oxidative organic synthesis and water remediation, often neglecting recent advancements in plastic upgrading, biomass conversion, and H2O2 production, and failing to provide an in-depth discussion of catalytic mechanisms. This review addresses these gaps by offering a comprehensive overview of recent advancements in dual-channel redox reactions for photocatalytic H2-evolution and waste photoreforming. It highlights waste-to-wealth design concepts, examines the challenges, advantages and diverse applications of dual-channel photocatalytic reactions, including photoreforming of biomass, alcohol, amine, plastic waste, organic pollutants, and H2O2 production. Emphasizing improvement strategies and exploration of catalytic mechanisms, it includes advanced in-situ characterization, spin capture experiments, and DFT calculations. By identifying challenges and future directions in this field, this review provides valuable insights for designing innovative dual-channel photocatalytic systems.
期刊介绍：
The journal covers a broad scope, encompassing new trends in catalysis for applications in energy production, environmental protection, and the preparation of materials, petroleum chemicals, and fine chemicals. It explores the scientific foundation for preparing and activating catalysts of commercial interest, emphasizing representative models.The focus includes spectroscopic methods for structural characterization, especially in situ techniques, as well as new theoretical methods with practical impact in catalysis and catalytic reactions.The journal delves into the relationship between homogeneous and heterogeneous catalysis and includes theoretical studies on the structure and reactivity of catalysts.Additionally, contributions on photocatalysis, biocatalysis, surface science, and catalysis-related chemical kinetics are welcomed.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
