通过界面结构设计协同增强 Nextel 610/SiOC 复合材料的机械性能和宽带吸收性能

IF 5.8 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of The European Ceramic Society Pub Date : 2024-10-21 DOI:10.1016/j.jeurceramsoc.2024.117002
Fan Yang , Yuan Gao , Yuqiu Wang , Jimei Xue , Benzheng Gao , Zeyou Tong , Shangwu Fan , Xiaomeng Fan
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引用次数: 0

摘要

本研究采用化学气相渗透(CVI)方法制备了 BN 中间相和 Si3N4 基体,以优化 N610/SiOC 复合材料的力学性能,并研究了其增强和增韧机理。结果表明,Si3N4 基体的含量和分布以及 BN 间相的厚度可同时调节复合材料的强度和韧性。BN 相间厚度为 540 nm 的 Si3N4 增强 N610/SiOC 复合材料分别获得了 234 MPa 的最佳拉伸强度和 338 MPa 的最佳弯曲强度。同时,为了优化宽带电磁波吸收,还设计了游离碳改性 BN 相(BN(C))和多层 "榫卯 "连接。阻抗匹配的 "榫卯 "连接实现了 8.4 GHz 的宽有效吸收带宽(EAB)和 -52.55 dB 的最小反射损耗(RLmin)。这项工作启发了设计和制造具有良好机械性能和宽带电磁波吸收性能的 CMC。
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Mechanical and broadband absorption properties of Nextel 610/SiOC composites synergistically enhanced by the interfacial structure design
In this work, BN interphase and Si3N4 matrix were prepared by chemical vapor infiltration (CVI) to optimize the mechanical properties of N610/SiOC composites, and the strengthening and toughening mechanisms were investigated. The results showed that the content and distribution of Si3N4 matrix and the thickness of BN interphase could tailor the strength and toughness of composites simultaneously. The optimal tensile strength of 234 MPa and flexural strength of 338 MPa were obtained by Si3N4 reinforced N610/SiOC composites with a BN interphase thickness of 540 nm, respectively. Meanwhile, free carbon modified BN interphase (BN(C)) and multi-layer “mortise and tenon” joint were designed to optimize the broadband EMW absorption. The impedance-matching “mortise and tenon” joint achieved a wide effective absorption bandwidth (EAB) of 8.4 GHz and a minimum reflection loss (RLmin) of −52.55 dB. This work inspires designing and fabricating CMC with both good mechanical and broadband EMW absorption properties.
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来源期刊
Journal of The European Ceramic Society
Journal of The European Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
10.70
自引率
12.30%
发文量
863
审稿时长
35 days
期刊介绍: The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.
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