The impact of relative humidity on the nanoindentation relaxation in calcium silicate hydrates

Despite extensive research efforts, understanding the time-dependent behavior of concrete remains an enigma due to the complex nature of cement microstructure. In this study, the statistical nanoindentation was employed to investigate the influence of relative humidity (RH) on the relaxation behavior of calcium silicate hydrates (C-S-H) in a cement paste. Our experiments, performed at RH levels of 33 % and 86 %, revealed significant enhancements in both the indentation modulus and hardness of the C-S-H as RH increased. Remarkably, the internal water exerted a significant influence on the asymptotic relaxation behavior, displaying a clear power-law fashion. Further analysis identified the presence of short- and long-term viscoelastic behaviors within the C-S-H, distinguished by a transition observed within the initial seconds. These findings advance the understanding of nanoscale mechanisms driving concrete creep under different humidity conditions.