研究相容聚氯乙烯/聚乳酸纳米复合材料的机械性能 研究相容聚氯乙烯/聚乳酸纳米复合材料的机械性能

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Materialwissenschaft und Werkstofftechnik Pub Date : 2024-08-21 DOI:10.1002/mawe.202300361
M. Khamisinasab, A. Azizi, M. Najafi, R. Aghazadeh, M.H. Bagherian
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引用次数: 0

摘要

由于可以选择多种材料并设计出具有所需性能的产品,因此聚合物合金尤其重要。如果各成分之间不相容,所制成的合金就无法满足所需的性能要求,性能也会变差。本研究在内部混合器中制备了聚氯乙烯和聚乳酸合金,并使用纳米粘土和马来酸酐接枝苯乙烯-乙烯/丁烯-苯乙烯(SEBS-g-MAH)相容剂来改善其性能。为了研究聚乳酸的形态和相分布,对其进行了扫描电子显微镜成像。拉伸和动态机械热分析测试用于评估样品的性能。扫描电子显微镜测试图像显示,合金中添加相容剂后,体系的均匀性得到了改善。在合金中添加纳米粘土提高了体系的储存模量和均匀性。含有相容剂的样品的玻璃化转变温度和储存模量都有所提高,体系的均匀性也得到了改善。拉伸试验结果表明,纳米粘土的添加量达到 3%(重量百分比)时,拉伸强度和杨氏模量都有所提高。相容剂的添加量达到 5%(重量百分比)时,物理和机械性能都有所提高。
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Investigation of mechanical properties of compatibilized polyvinyl chloride/polylactic acid nanocomposites Untersuchung der mechanischen Eigenschaften von kompatibilisierten Polyvinylchlorid-Milchsäure-Nanoverbundwerkstoffen

Polymer alloying is particularly important due to the possibility of choosing a wide range of materials and the ability to design a product with desired properties. In case of incompatibility between the components, the resulting alloy cannot meet the set of desired properties and shows poor performance. In this research, alloys of polyvinyl chloride and polylactic acid were prepared in an internal mixer and nanoclay and maleic anhydride-grafted styrene-ethylene/butylene-styrene (SEBS-g-MAH) compatibilizer were used to improve the properties. In order to investigate the morphology and phase distribution of polylactic acid, scanning electron microscope images were taken. Tensile and dynamic mechanical thermal analysis tests were performed to evaluate the properties of the samples. The scanning electron microscope test images show the improvement of system uniformity by adding compatibilizer to the alloy. Adding nanoclay to the alloy increased the storage modulus and uniformity of the system. An increase in glass transition temperature and storage modulus was observed in the samples containing compatibilizer, and the uniformity of the system was also improved. The tensile test results showed that by adding nanoclay up to 3 % by weight, the tensile strength and Young′s modulus increase. Addition of compatibilizer up to 5 % by weight increased the physical and mechanical properties.

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来源期刊
Materialwissenschaft und Werkstofftechnik
Materialwissenschaft und Werkstofftechnik 工程技术-材料科学:综合
CiteScore
2.10
自引率
9.10%
发文量
154
审稿时长
4-8 weeks
期刊介绍: Materialwissenschaft und Werkstofftechnik provides fundamental and practical information for those concerned with materials development, manufacture, and testing. Both technical and economic aspects are taken into consideration in order to facilitate choice of the material that best suits the purpose at hand. Review articles summarize new developments and offer fresh insight into the various aspects of the discipline. Recent results regarding material selection, use and testing are described in original articles, which also deal with failure treatment and investigation. Abstracts of new publications from other journals as well as lectures presented at meetings and reports about forthcoming events round off the journal.
期刊最新文献
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