通过 NiO/NiCo2O4 和碳层的异质结构耦合增强光催化的界面电荷转移

IF 4.3 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Journal of Physics and Chemistry of Solids Pub Date : 2024-10-24 DOI:10.1016/j.jpcs.2024.112404
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引用次数: 0

摘要

构建异质复合材料是提高光催化性能的一种有前途的策略。本研究采用煅烧法在石英砂表面涂覆碳层。此外,还在碳层上负载了 NiO/NiCo2O4 异质结构,以促进电荷转移并提高光生电子产率。精心设计的 QSC@NiO/NiCo2O4 异质结具有高效的界面电荷转移通道,从而提高了污染物降解能力。结果表明,在 120 分钟的光照条件下,RhB 和 MB 的去除率分别达到 94.75% 和 93.55%。经过 5 次循环后,RhB 和 MB 的去除率一直很高,分别达到 83.74 % 和 77.42 %。此外,还进行了攻丝实验,以探索光催化降解的机理。
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Enhanced interface charge transfer through heterostructure coupling of NiO/NiCo2O4 and carbon layer for photocatalysis
Constructing heterogeneous composite materials is a promising strategy for enhancing photocatalytic performance. In this study, the calcination method was employed to coat a carbon layer onto the surface of quartz sand. Additionally, NiO/NiCo2O4 heterostructures were loaded onto the carbon layer to facilitate charge transfer and enhance photo-generated electron yield. The carefully designed QSC@NiO/NiCo2O4 heterojunction possesses an efficient interface charge transfer channel, thereby improving contaminant degradation capacity. The results demonstrated that under 120 min of light exposure, the removal efficiencies for RhB and MB reached 94.75 % and 93.55 %, respectively. After undergoing 5 cycles, both RhB and MB exhibited consistently high elimination rates with values of 83.74 % and 77.42 %, respectively. Furthermore, tapping experiments were conducted to explore the mechanism of photocatalytic degradation.
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来源期刊
Journal of Physics and Chemistry of Solids
Journal of Physics and Chemistry of Solids 工程技术-化学综合
CiteScore
7.80
自引率
2.50%
发文量
605
审稿时长
40 days
期刊介绍: The Journal of Physics and Chemistry of Solids is a well-established international medium for publication of archival research in condensed matter and materials sciences. Areas of interest broadly include experimental and theoretical research on electronic, magnetic, spectroscopic and structural properties as well as the statistical mechanics and thermodynamics of materials. The focus is on gaining physical and chemical insight into the properties and potential applications of condensed matter systems. Within the broad scope of the journal, beyond regular contributions, the editors have identified submissions in the following areas of physics and chemistry of solids to be of special current interest to the journal: Low-dimensional systems Exotic states of quantum electron matter including topological phases Energy conversion and storage Interfaces, nanoparticles and catalysts.
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